4. Hemiacetals are the product of a reaction between an aldehyde and one equivalent of alcohol. Similarly, hemiketals form by a reaction between a ketone and one equivalent of alcohol. The reaction can be either inter- or intramolecular. The general structures are: 4.1 Complete the following reaction with the corresponding Hemiacetal/Hemiketal. O H3C H OH olanlarson CH3 + H3C H + OH CH3CH₂OH H + CH3OH CH₂OCH3 4.2 Identify the aldehyde and alcohol that will form the following products. OH HOR¹ R hemiacetal هم H3C HO OH R3 OH OR¹ 4.3 Write a complete arrow-pushing mechanism for the following hemiacetal formation under acid- catalyzed conditions. Use H-A to represent the acid catalyst. R hemiketal ܐ ܗ ܙ ܗ >
4. Hemiacetals are the product of a reaction between an aldehyde and one equivalent of alcohol. Similarly, hemiketals form by a reaction between a ketone and one equivalent of alcohol. The reaction can be either inter- or intramolecular. The general structures are: 4.1 Complete the following reaction with the corresponding Hemiacetal/Hemiketal. O H3C H OH olanlarson CH3 + H3C H + OH CH3CH₂OH H + CH3OH CH₂OCH3 4.2 Identify the aldehyde and alcohol that will form the following products. OH HOR¹ R hemiacetal هم H3C HO OH R3 OH OR¹ 4.3 Write a complete arrow-pushing mechanism for the following hemiacetal formation under acid- catalyzed conditions. Use H-A to represent the acid catalyst. R hemiketal ܐ ܗ ܙ ܗ >
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.26P: The compound eutypine is an antibacterial agent isolated from the fungus Eutypa lata. This fungus...
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