3. From the following compounds below, label the most reactive species in a Diels Alder reaction and explain why. A. B. C. Bis THE mose Readine SINCE it is in " ciscanforation But he HAS T BOND MAKING IT SUITABLE A PAIR of Conjugad
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- MATCHa structuceor.term.from the tollowing list.with.each description belom Plas the structure.or.term.inthe blank to.the Jeft.of.the description a. F-TEDA-BF b. NO d. electron-donating E. electron-withdrawing The reactive electrophile in Friedel-Crafts acylation reactions 28, The electrophile in aromatic nitration 29.- bstitution. Groups which activate aromatic rings towards electrophilic su 30 Source of F* in fluorination reactions. 31.With reference to anion A, label compounds B–E as an isomer orresonance structure of A. For each isomer, indicate what bonds differfrom A.The following alkenes undergo Diels-Alder reactions EXCEPT: А. В. | D. C. NC, ||
- Rank the following according to DECREASING reactivity towards E2: Br H,C CH, Br H. CH, Br H,C. CH Br CH H. H.C CH, H. H. H. H. CH H. H. GHI JKL MNO POR Ist (most reactive) Choose 2nd Choose 3rd Choose 4th (least reactive) Choose. cofthe folowing s the correct IURAC rame.of.the compouna be oIn a Diels-Alder Reaction, an "endo" group: (Choose all correct answers) Is on the same side as the larger bridge b. Is on the same side as the smaller bridge c. Is drawn down by convention d. Is drawn out by conventionBased on these configurations of peroxide, assign their respective point groups and explain why. a. H C. H O H H C b. d. H H O- ||| Ill...
- f. 2. Show g. its) H,, D Br LDA OH 0 you would prepare the following molecule from th12.47 What diene and dienophile are needed to prepare each Diels-Alder product? a. b. free C. d. e. f. CNWhat diene and dienophile are needed to prepare the following Diels-Alder product? O b. OC O d. O e. O f. + + + + + + O