25.00 mL of 0.041 32 M Hg₂(NO3)2 were titrated with 0.057 89 M KIO3. Hg2+ + 2103 → Hg2(103)2(s) lodate For Hg₂ (103)2, Kp = 1.3 X 10-¹8. Find [Hg3*] in the solution after addition of (a) 34.00 mL of KIO3; (b) 36.00 mL of KIO3; and (c) at the equivalence point.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter22: An Introduction To Electroanalytical Chemistry
Section: Chapter Questions
Problem 22.10QAP
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Analytical Chemistry part 2
25.00 mL of 0.041 32 M Hg₂(NO3)2 were titrated with 0.057 89 M KIO3.
Hg₂+ + 2103 → → Hg₂(103)2(S)
lodate
For Hg2 (103)2, Kp = 1.3 X 10-¹8. Find [Hg2+] in the solution after addition of (a) 34.00 mL
of KIO3; (b) 36.00 mL of KIO3; and (c) at the equivalence point.
Find [Hg₂²+] at 34.50 and 36.5 mL. Compute as well the pHg for all the points.
Transcribed Image Text:25.00 mL of 0.041 32 M Hg₂(NO3)2 were titrated with 0.057 89 M KIO3. Hg₂+ + 2103 → → Hg₂(103)2(S) lodate For Hg2 (103)2, Kp = 1.3 X 10-¹8. Find [Hg2+] in the solution after addition of (a) 34.00 mL of KIO3; (b) 36.00 mL of KIO3; and (c) at the equivalence point. Find [Hg₂²+] at 34.50 and 36.5 mL. Compute as well the pHg for all the points.
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