200 200 5 / 5 The data you have been reviewing has been idealized data-data that has been created using a drawing program. Real data is a bit different! Here is a real DEPT spectrum (obtained from the Univ. of Southern Maine) of propyl benzoate, with CNMR below it: Real peaks in DEPT-90 are the same height in all three spectra. CD-03- 160 150 140 75% 120 100 + 100 ppm 00 The "Bleed over peaks" 50 PPM Notice the "bleed over peaks" in the DEPT-90 spectrum - this happens often, but are NOT REAL PEAKS! Real peaks in the DEPT-90 spectrum will be the same height in all three DEPT spectra. Use the DEPT data to assign as many peaks as you can in propyl benzoate.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 8E
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200
200
5 / 5
The data you have been reviewing has been idealized data-data that has been created using a
drawing program. Real data is a bit different! Here is a real DEPT spectrum (obtained from the Univ. of
Southern Maine) of propyl benzoate, with CNMR below it:
Real peaks in
DEPT-90 are the
same height in all
three spectra.
180
CD-03-80
160
150
140
75%
120
100
+
100
90
"Bleed over peaks"
PPM
Notice the "bleed over peaks" in the DEPT-90 spectrum - this happens often, but are NOT REAL
PEAKS! Real peaks in the DEPT-90 spectrum will be the same height in all three DEPT spectra.
Use the DEPT data to assign as many peaks as you can in propyl benzoate.
Transcribed Image Text:200 200 5 / 5 The data you have been reviewing has been idealized data-data that has been created using a drawing program. Real data is a bit different! Here is a real DEPT spectrum (obtained from the Univ. of Southern Maine) of propyl benzoate, with CNMR below it: Real peaks in DEPT-90 are the same height in all three spectra. 180 CD-03-80 160 150 140 75% 120 100 + 100 90 "Bleed over peaks" PPM Notice the "bleed over peaks" in the DEPT-90 spectrum - this happens often, but are NOT REAL PEAKS! Real peaks in the DEPT-90 spectrum will be the same height in all three DEPT spectra. Use the DEPT data to assign as many peaks as you can in propyl benzoate.
Use the spectra on page 5 of the activity and the structure below to assign the CNMR
spectrum for propyl benzoate.
d
oby
b
9
The peak at -168 ppm corresponds to carbon [Select]
The small peak at ~130 ppm corresponds to carbon [Select]
The peak at -66 ppm corresponds to carbon [Select]
The peat at -22 ppm corresponds to carbon [Select]
Transcribed Image Text:Use the spectra on page 5 of the activity and the structure below to assign the CNMR spectrum for propyl benzoate. d oby b 9 The peak at -168 ppm corresponds to carbon [Select] The small peak at ~130 ppm corresponds to carbon [Select] The peak at -66 ppm corresponds to carbon [Select] The peat at -22 ppm corresponds to carbon [Select]
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