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20.9 (a) Explain the forms of the d orbital splitting diagrams for trigonal bipyramidal and square pyramidal complexes of formula ML5 shown in Fig. 20.11. (b) What would you expect concerning the magnetic properties of such complexes of Ni(II)?

20.9 (a) Explain the forms of the d orbital splitting diagrams for trigonal bipyramidal and square pyramidal complexes of formula ML5 shown in Fig. 20.11. (b) What would you expect concerning the magnetic properties of such complexes of Ni(II)?

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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20.9 (a) Explain the forms of the d orbital splitting diagrams for trigonal bipyramidal and square pyramidal complexes of formula ML5 shown in Fig. 20.11. (b) What would you expect concerning the magnetic properties of such complexes of Ni(II)?
Transcribed Image Text:20.9 (a) Explain the forms of the d orbital splitting diagrams for trigonal bipyramidal and square pyramidal complexes of formula ML5 shown in Fig. 20.11. (b) What would you expect concerning the magnetic properties of such complexes of Ni(II)?
Energy/Act 25 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 -0.1 -0.2 -0.3 -0.4 -0.5 -0.6 -0.7 d₂2,2 d xy 1/02/04 dyz dyz Square planar d₂2 dy d 2,2 d d yz d₂2² d-2 xy d d d2 d2,2 dy d d xy yz xy d.2 d 2,2 d. dyz XZ d. d XZ dxy d 2,2 d₂2 Pentagonal Square bipyramidal antiprismatic dy dz dz xy yz d₂2 d₂2, 2 Trigonal Square Octahedral bipyramidal pyramidal Fig. 20.11. Crystal field splitting diagrams for some common fields referred to a common barycentre. Splittings are given with respect to Aoct- Tetrahedral
Transcribed Image Text:Energy/Act 25 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 -0.1 -0.2 -0.3 -0.4 -0.5 -0.6 -0.7 d₂2,2 d xy 1/02/04 dyz dyz Square planar d₂2 dy d 2,2 d d yz d₂2² d-2 xy d d d2 d2,2 dy d d xy yz xy d.2 d 2,2 d. dyz XZ d. d XZ dxy d 2,2 d₂2 Pentagonal Square bipyramidal antiprismatic dy dz dz xy yz d₂2 d₂2, 2 Trigonal Square Octahedral bipyramidal pyramidal Fig. 20.11. Crystal field splitting diagrams for some common fields referred to a common barycentre. Splittings are given with respect to Aoct- Tetrahedral
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