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- 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH, Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH,CH,CH,CH,CCH, Br b) For the major elimination product obtained in 5a), which stereoisonmer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.2. The following carbocation is generated as an intermediate in the addition of H-Br to an alkene. Draw the structure of all possible alkenes that could have formed this intermediate.
- Draw the alkene that would react with the reagent given to account for the product formed. ? + + H₂O **** H₂S04 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. CH3 CH3 CHCCH3 | | OH CH3 +112) Use the curved arrow formalism to show the movement of electron pairs in the following reaction and label each reactant as a nucleophile or an electrophile. CHÍNH CHỊCH, + CO Học Nha CH₂CH₂CIThe pictured reaction shows an alkyl bromide being converted into an alkene. Choose all reagents that would produce the pictured alkene as the major product. A) NaOH/H2O B) H2O C) tBuOK/tBuOH D) EtONa/EtOH
- What about the second step in the electrophilic addition of HCl to an alkene-the reaction of chloride ion with the carbocation intermediate? Is this step exergonic or endergonic? Does the transition state for this second step resemble the reactant (carbocation) or the product (alkyl chloride)? Make a rough diagram of what the transition state may look like?Draw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy asteComplete each hydrogenation reaction. catalyst a. CH2=CH-CH3 + H2 catalyst b. CH3-CH-CH=CH2 + H2 ČH3 catalyst c. с. CH, —CH—С—СH, + H, ČH; ČH;
- Which represents an efficient synthetic route to go from an alkane to an alkene? O elimination with NaNH2, followed by a water workup O anti-Markovnikov hydrohalogenation, followed by elimination O radical bromination, followed by elimination O hydration, followed by elimination O hydration, followed by ozonolysis of the double bond5. Classify the following reagents as either nucleophiles or electrophiles: Zn? CH;NH, , HS , OH; , CH;COOH , H,SO,5. Synthesis: Synthesize the following compound from cyclohexane, any carbon pieces that are three carbons or less (can include other functional groups), and any inorganic reagents.