19. Rank the nucleophilicity for halides: a. F> Cl > Br >I b. Cl>F> Br >I c. I> Br> Cl>F d. I> Cl > Br >F 20. What mechanism is/are involved in the reaction below? CH,OH heat Br ÓCH, a. SN1 & El b. SN1 & E2 c. SN2 & E1 d. SN2 & E2 21. What is the reagent used for the following reaction? IOH a. BH3/THF, then H2O2/OH b. Hg(OAc)2/H2O, then NaBH4 с. Н.О, Н d. H2, Pd/C

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Can you solve all
etion?
19. Rank the nucleophilicity for halides:
a. F> Cl > Br >I
b. Cl>F> Br > I*
c. I > Br> Cl >F
d. I> Cl > Br >F
20. What mechanism is/are involved in the reaction below?
CH,OH
heat
Br
OCH,
a. SN1 & El
b. SN1 & E2
c. SN2 & E1
d. SN2 & E2
21. What is the reagent used for the following reaction?
8.
IOH
a. BH3/THF, then H2O2/OH
b. Hg(OAc)2/H2O, then NaBH4
с. Н-О, Н"
d. H2, Pd/C
22. What is the major product for reaction below?
H,SO4
below
а.
d. none
23. Arrange the following substrates in order of increasing their SN2 reactivity with NaCN:
(1). bromoethane,
(3). 1-chloro-2,2-dimethylpentane,
(2). 1-chloro-3,3-dimethylpentane,
(4). 2-bromo-2-methylpentane.
a. 1<2<3<4
b. 4 <3 < 2 <1
c. 2 <3 <1 <4
d. 3 <1<2<4
24. Identify the alkyl halide that most favorites an SN2 mechanism.
a. CH3CH2CH2B1;
b. CH3CHBrCH2CH3;
c. CH3C(CH3)BrCH2CH3;
d. CH3Br
4
Transcribed Image Text:etion? 19. Rank the nucleophilicity for halides: a. F> Cl > Br >I b. Cl>F> Br > I* c. I > Br> Cl >F d. I> Cl > Br >F 20. What mechanism is/are involved in the reaction below? CH,OH heat Br OCH, a. SN1 & El b. SN1 & E2 c. SN2 & E1 d. SN2 & E2 21. What is the reagent used for the following reaction? 8. IOH a. BH3/THF, then H2O2/OH b. Hg(OAc)2/H2O, then NaBH4 с. Н-О, Н" d. H2, Pd/C 22. What is the major product for reaction below? H,SO4 below а. d. none 23. Arrange the following substrates in order of increasing their SN2 reactivity with NaCN: (1). bromoethane, (3). 1-chloro-2,2-dimethylpentane, (2). 1-chloro-3,3-dimethylpentane, (4). 2-bromo-2-methylpentane. a. 1<2<3<4 b. 4 <3 < 2 <1 c. 2 <3 <1 <4 d. 3 <1<2<4 24. Identify the alkyl halide that most favorites an SN2 mechanism. a. CH3CH2CH2B1; b. CH3CHBrCH2CH3; c. CH3C(CH3)BrCH2CH3; d. CH3Br 4
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Absorption and Adsorption
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY