16.96 Experiment shows that the rate of formation of carbon tetrachloride from chloroform, CHCl3 (g) + Cl2 (g) → CCl4 (g) + HCl (g) 1 3 is first order in CHCl3, order in Cl₂, and order overall. Show that the following mechanism is consistent with the rate law: (1) Cl₂ (g)=2C1 (g) [fast] (2) C1 (g) + CHCl3 (g) → HCl (g) + CC13 (g) [slow] (3) CC13 (g) +Cl (g) → CC14 (g) [fast]

16.96 Experiment shows that the rate of formation of carbon tetrachloride from chloroform, CHCl3 (g) + Cl2 (g) → CCl4 (g) + HCl (g) 1 3 is first order in CHCl3, order in Cl₂, and order overall. Show that the following mechanism is consistent with the rate law: (1) Cl₂ (g)=2C1 (g) [fast] (2) C1 (g) + CHCl3 (g) → HCl (g) + CC13 (g) [slow] (3) CC13 (g) +Cl (g) → CC14 (g) [fast]

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.77QE

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