13. What is the entropy change for the following reaction (which needs to be balanced)? N2O4(g) E> O2(g) + N2O(g) a. 447 J/mol•K b. 477 J/mol•K c. 121 J/mol•K d. 783 J/mol•K 14. In the reaction of aqueous silver (I) nitrate and aqueous sodium chloride to form aqueous sodium nitrate and solid silver (I) chloride, what is oxidized and what is reduced? a. Silver is oxidized, sodium is reduced b. Silver is oxidized, nitrate is reduced c. Sodium is oxidized, chloride is reduced d. Nothing is oxidized or reduced

13. What is the entropy change for the following reaction (which needs to be balanced)? N2O4(g) E> O2(g) + N2O(g) a. 447 J/mol•K b. 477 J/mol•K c. 121 J/mol•K d. 783 J/mol•K 14. In the reaction of aqueous silver (I) nitrate and aqueous sodium chloride to form aqueous sodium nitrate and solid silver (I) chloride, what is oxidized and what is reduced? a. Silver is oxidized, sodium is reduced b. Silver is oxidized, nitrate is reduced c. Sodium is oxidized, chloride is reduced d. Nothing is oxidized or reduced

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter16: Thermodynamics: Directionality Of Chemical Reactions

Section: Chapter Questions

Problem 113QRT

See similar textbooks

Similar questions

9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in water: NH4NO3(s)NH4+(aq)+NO3(aq) H= 25.69 kJ A particular cold pack contains 50.0 g of NH4NO3 and 125.0 g of water. When the pack is squeezed, the NH4NO3dissolves in the water. If the pack and its contents are initially at 24.0°C, what is the lowest temperature that this bag could reach? (Assume that the ammonium nitrate solution has a specific heat of 4.25J g-l K-l, and that the heat capacity of the bag itself is small enough to be neglected.)
What is the third law of thermodynamics? What are standard entropy values, S, and how are these S values (listed in Appendix 4) used to calculate S for a reaction? How would you use Hesss law to calculate S for a reaction? What does the superscript indicate? Predicting the sign of S for a reaction is an important skill to master. For a gas-phase reaction, what do you concentrate on to predict the sign of S? For a phase change, what do you concentrate on to predict the sign of S? That is, how are Ssolid, Sliquid, and Sgas related to one another? When a solute dissolves in water, what is usually the sign of S for this process?
A key component in many chemical engineering designs is the separation of mixtures of chemicals. (a) What happens to the entropy of the system when a chemical mixture is separated? (b) Are designs for chemical separation more likely to rely on spontaneous or nonspontaneous processes?
The free energy change, G, for a process at constant temperature and pressure is related to Suniv and reflects the spontaneity of the process. How is G related to Suniv? When is a process spontaneous? Nonspontaneous? At equilibrium? G is a composite term composed of H, T, and S. What is the G equation? Give the four possible sign combinations for H and S. What temperatures are required for each sign combination to yield a spontaneous process? If G is positive, what does it say about the reverse process? How does the G = H TS equation reduce when at the melting-point temperature of a solid-to-liquid phase change or at the boiling-point temperature of a liquid-to-gas phase change? What is the sign of G for the solid-to-liquid phase change at temperatures above the freezing point? What is the sign of G for the liquid-to-gas phase change at temperatures below the boiling point?
When solid sodium acetate crystallizes from a supersaturated solution, can you accurately predict the sign of H for the crystallization? Why or why not?
The decomposition of diamond to graphite [C(diamond) C(graphite)] is thermodynamically favored, but occurs slowly at room temperature. a. Use fG values from Appendix L to calculate rG and Keq for the reaction under standard conditions and 298.15 K. b. Use fH and S values from Appendix L to estimate rG and Keq for the reaction at 1000 K. Assume that enthalpy and entropy values are valid at these temperatures. Does heating shift the equilibrium toward the formation of diamond or graphite? c. Why is the formation of diamond favored at high pressures? d. The phase diagram shows that diamond is thermodynamically favored over graphite at 20,000 atmospheres pressure (about 2 GPa) at room temperature. Why is this conversion actually done at much higher temperatures and pressures?