100 139 MS-NW-3158 80 111 [M]* 20 [M+2]* 25 50 75 100 125 150 m/z Relative Intensity 유

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter7: Components Of Optical Instruments
Section: Chapter Questions
Problem 7.16QAP
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The mass spectrum of compound E with the molecular formula C8H7ClO is shown below.

Draw the most likely ion fragment for the signals at m/z 111 and 139.

Why do these signals at m/z 113, 141, and 156 appear as pairs with similar intensities at m/z 111, 139, and 154?

100
HS-NW-3158
139
80
111
[M]*
20
[M+2]*
25
50
75
100
125
150
m/z
Relative Intensity
유
Transcribed Image Text:100 HS-NW-3158 139 80 111 [M]* 20 [M+2]* 25 50 75 100 125 150 m/z Relative Intensity 유
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