1.2. Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated. Element Ni ZUHO ZREN C Н Ag Co Cr Fe Pt Zn Atomic Radius Crystal Electro- (nm) Structure negativity Valence FCC 1.8 +2 0.1246 0.071 0.046 0.060 0.1445 0.1431 0.1253 0.1249 0.1241 0.1387 0.1332 FCC FCC HCP BCC BCC FCC HCP 1.9 1.5 1.8 1.6 1.8 2.2 1.6 +1 +3 +2 +3 +2 +2 +2 a) Which of these elements would you expect to form the following with nickel: i) A substitutional solid solution having complete solubility ii) A substitutional solid solution of incomplete solubility iii) An interstitial solid solution

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter3: Atomic Shells And Classical Models Of Chemical Bonding
Section: Chapter Questions
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1.2. Below, atomic radius, crystal structure, electronegativity, and the most common
valence are tabulated, for several elements; for those that are nonmetals, only
atomic radii are indicated.
Element
Ni
C
H
Ag
ROUREN
Co
Cr
Fe
Pt
Zn
Atomic
Radius Crystal Electro-
(nm) Structure
FCC
0.1246
0.071
0.046
0.060
0.1445
0.1431
0.1253
0.1249
0.1241
0.1387
0.1332
FCC
FCC
HCP
BCC
BCC
FCC
HCP
negativity Valence
1.8
+2
1.9
1.5
1.8
1.6
1.8
2.2
1.6
+1
+3
+2
+3
+2
+2
+2
a) Which of these elements would you expect to form the following with nickel:
i) A substitutional solid solution having complete solubility
ii) A substitutional solid solution of incomplete solubility
iii) An interstitial solid solution
b) Why is it important to know the type of solid solution formed?
c) How many phases are present in each solution?
d) What type of defects are present in a)(ii) and (iii), besides the fact that solid
solutions are point defects and have impurity atoms.
Transcribed Image Text:1.2. Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated. Element Ni C H Ag ROUREN Co Cr Fe Pt Zn Atomic Radius Crystal Electro- (nm) Structure FCC 0.1246 0.071 0.046 0.060 0.1445 0.1431 0.1253 0.1249 0.1241 0.1387 0.1332 FCC FCC HCP BCC BCC FCC HCP negativity Valence 1.8 +2 1.9 1.5 1.8 1.6 1.8 2.2 1.6 +1 +3 +2 +3 +2 +2 +2 a) Which of these elements would you expect to form the following with nickel: i) A substitutional solid solution having complete solubility ii) A substitutional solid solution of incomplete solubility iii) An interstitial solid solution b) Why is it important to know the type of solid solution formed? c) How many phases are present in each solution? d) What type of defects are present in a)(ii) and (iii), besides the fact that solid solutions are point defects and have impurity atoms.
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