1. Give the structures of the products obtained when the following are heated: Ph Me OMe b. a. O2N Ph

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter7: Alkynes
Section: Chapter Questions
Problem 7.35P
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Please help me with “d” and questions 2 and 3. Thank you!
1. Give the structures of the products obtained when the following are heated:
Ph
Me
OMe
b.
a.
O2N
Ph
C.
NC
CN
d.
2. Which compounds would you heat together in order to synthesize each of the
following?
CHO
3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl
groups in your product are cis with respect to each other. USING
STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct
in which the phenyl groups are cis. (HINT: Remember that there is free rotation
around single bonds, and study the discussion of the stereochemistry of the
Diels-Alder reaction in your text.)
Transcribed Image Text:1. Give the structures of the products obtained when the following are heated: Ph Me OMe b. a. O2N Ph C. NC CN d. 2. Which compounds would you heat together in order to synthesize each of the following? CHO 3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl groups in your product are cis with respect to each other. USING STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct in which the phenyl groups are cis. (HINT: Remember that there is free rotation around single bonds, and study the discussion of the stereochemistry of the Diels-Alder reaction in your text.)
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