1. Consider the reaction A + B products From the following data obtained at a certain temperature, determine the (a) rate law, (b) overall order of the reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment I) [A] (M) [B] (M) Rate (M/s) 1.50 1.50 3.20 × 10-1 1.50 3.00 3.20 × 10-¹ 1 3.00 1.50 6.40 X 10
1. Consider the reaction A + B products From the following data obtained at a certain temperature, determine the (a) rate law, (b) overall order of the reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment I) [A] (M) [B] (M) Rate (M/s) 1.50 1.50 3.20 × 10-1 1.50 3.00 3.20 × 10-¹ 1 3.00 1.50 6.40 X 10
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 35QAP: Azomethane decomposes into nitrogen and ethane at high temperatures according to the following...
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![1. Consider the reaction
A + B products
From the following data obtained at a certain temperature, determine the (a) rate law, (b) overall order of the
reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment
I)
[A] (M)
[B] (M)
Rate (M/s)
1.50
1.50
3.20 × 10-¹
1.50
3.00
3.20 × 10-¹
1
3.00
1.50
6.40 × 10
c.) 0.213/s
Answers: b). overall order of the reaction: first-order
Note: answer for letter a will be provided by the student.
2. The reaction of peroxydisulfate ion (S₂O) with iodide ion (I) is
|S₂O²¯(aq) + 31¯(aq) 2SO3(aq) + 13(aq)
From the following data collected at a certain temperature, determine the (a) rate law, (b) overall order of the
reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment
I)
Experiment
[S₂O²¯] (M)
Initial Rate (M/s)
[I] (M)
0.034
1
0.080
2.2 × 10-4
2
0.080
0.017
1.1 x 10-4
3
0.16
0.017
2.2 x 10-4
Answers: b). overall order of the reaction: second-order
Note: answer for letter a will be provided by the student.
c.) 8.1 x 102/M.s](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdb82b1bf-9ecb-4650-bc73-bb0c93237287%2F93fcb2eb-53f0-403a-9b68-418ff483d015%2Ffsf04ot_processed.png&w=3840&q=75)
Transcribed Image Text:1. Consider the reaction
A + B products
From the following data obtained at a certain temperature, determine the (a) rate law, (b) overall order of the
reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment
I)
[A] (M)
[B] (M)
Rate (M/s)
1.50
1.50
3.20 × 10-¹
1.50
3.00
3.20 × 10-¹
1
3.00
1.50
6.40 × 10
c.) 0.213/s
Answers: b). overall order of the reaction: first-order
Note: answer for letter a will be provided by the student.
2. The reaction of peroxydisulfate ion (S₂O) with iodide ion (I) is
|S₂O²¯(aq) + 31¯(aq) 2SO3(aq) + 13(aq)
From the following data collected at a certain temperature, determine the (a) rate law, (b) overall order of the
reaction and (c) calculate the rate constant (Show your complete solution and use the data from Experiment
I)
Experiment
[S₂O²¯] (M)
Initial Rate (M/s)
[I] (M)
0.034
1
0.080
2.2 × 10-4
2
0.080
0.017
1.1 x 10-4
3
0.16
0.017
2.2 x 10-4
Answers: b). overall order of the reaction: second-order
Note: answer for letter a will be provided by the student.
c.) 8.1 x 102/M.s
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