1. An aqueous solution is prepared that is initially 0.100 M Cdl2. After the equilibrium is established, the solution is found to be 0.013 M in Cd2+. The products of equilibrium are Cd2+ (aq)and I (aq). a) Write the expression of equilibrium constant b) Find the value of K. c) What will be the Cd2+ concentration, if 0.400M moles of KI is added to 1.00 L of the solution in the question. d) A solution is prepared by mixing 0.500 L of the solution from part c and mixed with 0.500 L of 2.0 X 10-5 m NaOH. Write the reaction. e) Will Cd (OH)2 precipitate. (HINT: Q is less than Ksp, there will be no precipitate) f) When the initial solution is heated, the Cd2+ increases. Is the equilibrium endothermic or exothermic and why?

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Chapter15: Equilibria Of Other Reaction Classes
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Problem 109E: The following question is taken from a Chemistry Advanced Placement Examination and is used with the...
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1. An aqueous solution is prepared that is initially 0.100 M
Cdla2. After the equilibrium is established, the solution is
found to be 0.013 M in Cd2+. The products of equilibrium
are Cd2+ (aq)and I' (aq).
a) Write the expression of equilibrium constant
b) Find the value of Ke
c) What will be the Cd2+ concentration, if 0.400M moles of
KI is added to 1.00 L of the solution in the question.
d) A solution is prepared by mixing 0.500 L of the solution
from part c and mixed with 0.500 L of 2.0 X 10-5 m
NaOH. Write the reaction.
e) Will Cd (OH)2 precipitate. (HINT: Q is less than Ksp, there
will be no precipitate)
f) When the initial solution is heated, the Cd2+ increases. Is
the equilibrium endothermic or exothermic and why?
Transcribed Image Text:1. An aqueous solution is prepared that is initially 0.100 M Cdla2. After the equilibrium is established, the solution is found to be 0.013 M in Cd2+. The products of equilibrium are Cd2+ (aq)and I' (aq). a) Write the expression of equilibrium constant b) Find the value of Ke c) What will be the Cd2+ concentration, if 0.400M moles of KI is added to 1.00 L of the solution in the question. d) A solution is prepared by mixing 0.500 L of the solution from part c and mixed with 0.500 L of 2.0 X 10-5 m NaOH. Write the reaction. e) Will Cd (OH)2 precipitate. (HINT: Q is less than Ksp, there will be no precipitate) f) When the initial solution is heated, the Cd2+ increases. Is the equilibrium endothermic or exothermic and why?
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