1) For each condensed or skeletal structure below: A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs. B. Indicate the hybridization of all C, O, and N atoms in each of the molecules. C. Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember, e.g. that a double bond is made up of both a o and a bond). Also indicate which orbitals overlap to form the bond (e.g., Ols-2sp³). D. For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located. E. Which of the bonds indicated by arrows is shorter? b) CH3

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter3: Electron Orbitals
Section: Chapter Questions
Problem 3CTQ
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1) For each condensed or skeletal structure below:
A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs.
B. Indicate the hybridization of all C, O, and N atoms in each of the molecules.
C.
Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember,
e.g. that a double bond is made up of both a o and a π bond). Also indicate which orbitals overlap to form
the bond (e.g., Ols-2sp3).
D.
For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located.
E. Which of the bonds indicated by arrows is shorter?
a)
c) H
CH3
C=CHC=C-CH
g) (CH3)3CCN
CH3
CH₂CH=CHCECH
b)
d)
CH3
Lo
LOH
f) CH₂CH(CH3)SH
h) (CH3)2CH(CH₂)3Br
Transcribed Image Text:1) For each condensed or skeletal structure below: A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs. B. Indicate the hybridization of all C, O, and N atoms in each of the molecules. C. Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember, e.g. that a double bond is made up of both a o and a π bond). Also indicate which orbitals overlap to form the bond (e.g., Ols-2sp3). D. For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located. E. Which of the bonds indicated by arrows is shorter? a) c) H CH3 C=CHC=C-CH g) (CH3)3CCN CH3 CH₂CH=CHCECH b) d) CH3 Lo LOH f) CH₂CH(CH3)SH h) (CH3)2CH(CH₂)3Br
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