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- H4)ConsiteR the following Beaction: Pa,t 8 H,0→ Hy POqt 3 HCl IP 12.49 of | 10.09 of Hy O, what is the limiting Ctrl PCI, is PeacteD witn T0.0g Peactant ? Molar nhass of Pelg: 137.329/mel. holarmass of HoO=18:0291 mel malar mass of Hy POz =¢2.00 glmol molar mass of HCl= 35.4A16 glmel. %3DauDUIUance UI U.I JU ai 4JJ IIII III 1. UU CIII cuvclic. Calculate the molar absorptivity of the pigment at 453 nm? Q5) A student is tasked to determine the number of moles of H2SO4 (aq) in a 200 ml of an unknown solution. The student prepares a series of solutions with known concentrations of H2SO4 (ag) and measures the absorbance of each at an appropriate wavelength. These data are used to construct the calibration plot shown below. 1.00 0.80- 0.60 - 0.40- 0.20- 0.00- 3 x 10-4 6 x 10-4 Concentration (mol/L) If the absorbance of the unknown solution is 0.70, how many moles of H2SO4 (aq) does the 200 ml sample contain? AbsorbancePart D Let that Za(OH) () is pely insoluble, which signs that the precipitation reaction with NaOH(aq) (pred in the transition) would go to completion Za (aq) + 2NaOH(aq) Zn(OH), () +2Na (₂) you had a 50 L son containing 200 M of Za" (aq) and you wished to add enough 1.30 M NaOH(aq) to precipitate at of the metal, what is the minimum amount of the NaOH(aq) solution you would As that the NaOH(o) son is the only ace of OEE (n) for the precipitation Capress the volume to three significant figures and include the appropriate View Av Haljuj ml. 7
- Solutions of cobalt (II) ions have a magenta color with a molar absorptivity constant (e) value at 511 nm of 5.87 M-1cm-1. A 0.500 mL sample is transferred from a 50.0 mL stock solution of Co(NO3)2 and diluted with water to a final volume of 7.50 mL. The dilution had an absorbance value at 511 nm in a standard cuvette (1.00 cm light path) of 0.382. Calculate the mass of Co(NO3)2 contained in the original 50.0 mL stock solution.(i) (ii) (iii) (iv) 'I OMe HO H g H N Me Br SnMe3 OSiMe3 CHO OH NaNH, NH3 (1) Phl, Pd(PPH3)4 THF, reflux 1. Ph3P=CMe2 2. "Bu4NF 3. H30 + CH₂12, Zn C C₂H₂NO D C₁1H₁1N E C10H16O F C15H26O2In the development o f an analytical method for the quantitative analysis o f iron using Atomic Absorption spectrophotometry (AAS), a linear calibration curve for standards o f 0.00, 5.00, 10.00, 15.00 and 20.00 ppm was prepared. An iron ore sample with an expected iron content o f 40-60% w/w is to be analysed by this method. An approximately 0.5-g sample is taken, dissolved in a minimum amount o f concentrated HC1 and diluted to 1 L in a volumetric flask using distilled water. A 5.00-mL aliquot is removed with a pipette. With explanation, to what volume (10, 25, 50, 100, 250 500 or 1000 mL) should the 5.00 mL aliquot be diluted, to minimize the uncertainty in the analysis?
- 6. Blue Blue dye stock solution 0.293 M Absorbance at 630 nm 0.00265 Calibration curve y = 0.0833x A solution is prepared by diluting 2.79 mL of the blue dye stock solution to 25.00 mL. The measured absorbance for the prepared solution is listed in the data table. (a) What is the theoretical molar concentration? [Blue]theoretical x 10 |M (b) What is the experimental molar concentration? [Blue]experimental x 10 M (c) What is the percent error? Percent error (blue) = %1. Question: Pd (1I), Au (III) methiomeprazine (C19 H24 N2S2) with the complex. A mixture of their complexesis being analyzed. Pd (II) complex at 480 nm, The measurement results for Au (III) with max peak at 635 nm are as follows. of the mixture What is the concentration?(b=1) Pd(II) Au(III) Mixture 480 nm 3,55x103 2,96x103 0,533 635 nm 5,641x0³ 1,45x10 0,590A solution of Tryptophan has an absorbance at 280 nm of 0.54 in a 0.5 cm length cuvette. Given the absorbance coefficient of trp is 6.4 x 103 Lmol-1cm-1. What is the concentration of solution?
- A Sample Containfng mmol of KNOS is "parsed 6.00 x10-2² mmol of vesay ad z.00x102 mmol af ves@y ad 2.00x1o2 though a cation -excharye Column. the Colculate. volume o.02.00 M NaH of needed to titrete the elwate,V = (2a/x)'/4e¬ax², , =?Calçulate Hhe selubility iA Mofeach of Hhe Salts BaSoy ksp zliS Xlo(9) 2 MgCofA)2 ksp= 9.0Xld-12) A9CN kse: 2.0X10(-12). Dfes ksp-3-7 xlo(-19) Ag2sksp:1.6x10(-49)
