. Answer the following, use the data and plot as a reference, answer the following questions: a) What volume of 0.100 M NaOH solution is required to reach the equivalence point, at which the solution is completely neutralized? b) Briefly explain why the pH of the solution drastically increases once the titration proceeds past the equivalence point. c) The end point in a titration of 50.00 mL of aqueous NaOH was reached by the addition of 35.23 mL of 0.250 M aqueous HCl titrant.  Calculate the molarity of

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8th Edition
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Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 51P
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1. Answer the following, use the data and plot as a reference, answer the following questions:
a) What volume of 0.100 M NaOH solution is required to reach the equivalence point, at which the solution is completely neutralized?
b) Briefly explain why the pH of the solution drastically increases once the titration proceeds past the equivalence point.
c) The end point in a titration of 50.00 mL of aqueous NaOH was reached by the addition of 35.23 mL of 0.250 M aqueous HCl titrant.  Calculate the molarity of the NaOH solution.  The titration reaction equation is:
NaOH (aq)  +  HCl (aq)  →  NaCl (aq)  +  H 2O (l)
Table of experimental data for the titration of an HCI
solution of unknown concentration with 0.100 M NaOH
solution
Volume of 0.100 M NaOH added (mL) pH of solution
0.0
1.00
5.0
1.18
10.0
1.37
15.0
1.60
20.0
1.95
22.0
2.20
24.0
2.69
24.5
3.00
24.9
3.70
25.0
7.00
25.1
10.30
25.5
11.00
26.0
11.29
28.0
11.75
30.0
11.96
35.0
12.22
40.0
12.36
45.0
12.46
50.0
12.52
Titration plot of strong acid HCl of unknown concentration with
0.100 M NaOH solution
14.00
13.00
12.00
11.00
10.00
9.00
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
55.0
Volume of 0.100 M NaOH added (mL)
pH of Solution
Transcribed Image Text:Table of experimental data for the titration of an HCI solution of unknown concentration with 0.100 M NaOH solution Volume of 0.100 M NaOH added (mL) pH of solution 0.0 1.00 5.0 1.18 10.0 1.37 15.0 1.60 20.0 1.95 22.0 2.20 24.0 2.69 24.5 3.00 24.9 3.70 25.0 7.00 25.1 10.30 25.5 11.00 26.0 11.29 28.0 11.75 30.0 11.96 35.0 12.22 40.0 12.36 45.0 12.46 50.0 12.52 Titration plot of strong acid HCl of unknown concentration with 0.100 M NaOH solution 14.00 13.00 12.00 11.00 10.00 9.00 8.00 7.00 6.00 5.00 4.00 3.00 2.00 1.00 0.00 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0 55.0 Volume of 0.100 M NaOH added (mL) pH of Solution
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