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Titration Lab

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The purpose of a titration is to discover the concentration of the unknown acid or base. In this case, the experiment uses a strong base to titrate the unknown acid. Once the titration is complete, the data is plotted to create a graph that shows the equivalence point as well as the change in pH with each volumetric addition of NaOH. The equivalence point in the graph is the point where the moles of acid equal the moles of base added, which can be expressed as the equation MaVa = MbVb. On any titration graph involving a monoprotic acid and a strong base, the equivalence point is the center of the steepest part of the graph, also known as the inflection point. This point will be at pH 7 or above, since the titrant is a strong base and the unknown …show more content…

The pKa is -log[Ka], and Ka is the equilibrium constant of a reaction. If there is a weak acid, it will have a strong conjugate base which will bond with a hydronium ion, causing the reaction to move towards the reactants which results in a lower Ka (or higher pKa). Therefore, the magnitude of the pKa has an effect on the equivalence point. A higher pKa results in a higher pH of the solution. The pKa also has several other implications. As the pKa increases, the initial pH increases as well. The initial slope of the graph is almost horizontal for a smaller pKa; however, as the pKa increases, the slope at the initial values increases as well. With further analysis, one can notice that the pH increases steadily between 5 and 20ml for all eight graphs but are placed at different pHs. This steady increase only lasts until the one drop of the titrant causes a jump from pHs. The range of the jump from one pH to another decreses as the pKa of a reaction increases. In other words, the range where the equivalence point occurs decreases. Despite the change in this range, the pKa (or Ka) does not affect the equivalence point volume since the same amount of acid was used in each experiment, which in turn means the same volume amount of NaOH is used as well. The changes in the pKa display changes in the equivalence point, pH, and slopes of the curve, all which ultimately

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