E. Cobham Brewer 18101897. Dictionary of Phrase and Fable. 1898.
Dunderhead.
A blockhead, or, rather, a muddle-headed person. Dunder is the lees or dregs of wine, etc., more correctly, the overflow of fermented liquors (yeast). (Spanish, redundar, to overflow or froth over.)
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The use of Dunder in the making of rum answers the purpose of yeast in the fermentation of flour.Edwards: West Indies.