Write out all elimination products from the following reactions including E,Z isomers. Rank the products based on stability which correlates with the amounts formed. -OH H₂SO4
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- What is (are) the predicted major product(s) for the reaction shown? I II III IV O O O₂N O₂N. O₂N O₂N HNO3/H2SO4 || ||| II and III O IV and I NO₂ -605 NO₂app.101edu.co Draw the major product of this reaction. Ignore inorganic byproducts. Assume that the water side product is continuously removed to drive the reaction toward products. esc F1 CH3CH2CH2OH H2SO4 (cat), heat ☀ F2 80 F3 OH a F4 W Q F5 Atoms and P Draw or ta MacBook A C F6What alkynes give each of the following ketones as the only product after hydration with H2O, H2SO4, and HgSO4?
- Q6. Fill in the blanks left in each of the following syntheses: Example: OH H Find the flaw(s): ОН H₂O* H CH3OH. Hº H ОН ОН H CO OCH3 0 MgBr NHANH2 КОН ОН оньсо H₂CO OCH; HBr Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:c. Snl reactions dominate under polar protic solvents. Increasing the polarity of the solvent will increase the rate of the reaction because the polar solvent will stabilize the dispersed charges on the transition state more than it will stabilize the neutral reactant. Label areas of ô* and & on the molecules of the transition state of the SN1 reaction below: Me Me Ме Me Me H20 Br -Br OH + НО \'H Et Et RDS Et H Et Et transition state not isolable carbocation intermediate not isolable
- For the reaction sequence below, provide the correct reagents, intermediate or final product. Br You? Na enant.Suggest a reasonable mechanism for the reaction shown Br here. HO CH;CH,OHOne of the steps in the mechanism of the above reaction as shown below. Draw the structure of all the products of this reaction. com/mm/takeAssignCourt Rotivity.do?locator assignment-take 1 pt ment Eto O Eto O 3. NaOH, H₂O, heat 4. HCI, H₂O, heat One of the steps in the mechanism of the above reaction is shown below. Draw the structure of all of the products of this reaction. O OEt O 1. Eto Na 2 Å OH You do not have to consider stereochemistry. • Draw enolate anions in their carbanion form. . You should include all products. Ôno P Ć [References) . Include counter-ions, e.g., Na, I, in your submission, but draw them in their own separate sketcher. . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. . Separate multiple products using the + sign from the drop-down menu. ///-000- IF Previous Email Instructor
- 3. Draw the systematic reaction mechanism for between the reaction of isoamyl alcohol and acetic acid What are the products? What is the functional group of the major product? Does it have a scent? If so, wha is the scent smells like? Choelie on Donio to malke dninl S 00/ ethang1. lohonatou Ilawe:Which set of conditions for the reaction given below would provide the largest amounts of substitution products? Conditions? substitution products NACN in DME NAOH in Water O NACN in MeOH NaF in DMFConsider the following overall reaction, which will be discussed in Chapter 20. H,C-CEN NH3 HOO H,C Below is a proposed mechanism for this reaction. Use the rules we learned in this chapter to evaluate whether each step in the proposed mechanism is reasonable. For each step that is not reasonable, explain why. :ÖH () H,C-CEN: H3C OH OH (i) + H,C H3C OH OH (ii) H,C H,C OH (iv) + H,O: H,C H,C OH (v) H3C H3C OH H. (vi) :NH, NH. H,C H,C