U U U CI Recall that the Friedel-Crafts alkylation reaction forms a new C-C bond between an aromatic ring and an alkyl halide, in the presence of an appropriate Lewis Acid. Which of the following (one or more than one) DO work well in Friedel-Crafts alkylation reactions? OH CI +a NO2 CI as the alkyl halide for the reaction
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- Recall that the Friedel-Crafts alkylation reaction forms a new C-C bond between an aromatic ring and an alkyl halide, in the presence of an appropriate Lewis Acid. Which of the following (one or more than one) DO work well in Friedel-Crafts alkylation reactions? ப n D NO2 CI as the alkyl halide for the reaction OH CI CI taWhich of the following is a weak nucleophile? OH- H2O CH3O-.Which one of the following molecules can react as electrophile in reactions with alkenes? CH3OH NaCI HCI KCN NaCI O HCI O KCN O CH3OH
- Br Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:Which reagent is the nucleophile in the esterification reaction shown below? O || С-ОН Benzoic Acid methanol methyl benzoate benzoic acid sulfuric acid + CH₂-OH Methanol H₂SO - H₂O O || C-O-CH3 Methyl benzoateH₂C=CHCCH3 then H3O+ The Michael reaction is a conjugate addition process wherein a nucleophilic enolate anion (the donor) reacts with an a,ß-unsaturated carbonyl compound (the acceptor). The best Michael reactions are those that take place when a particularly stable enolate anion is formed via treatment of the donor with a strong base. Alternatively, milder conditions can be used if an enamine is chosen as the donor, this variant is termed the Stork reaction. In the second step, the donor adds to the ẞ-carbon of the acceptor in a conjugate addition, generating a new enolate. The enolate abstracts a proton from solvent or from a new donor molecule to give the conjugate addition product. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions N 9a
- The given reaction scheme is an example of which type of reaction? O || R₁-C-OH + R₂-OH Oxidation Fischer esterification Nucleophilic substitution Reduction Rearrangement reaction Acid O || R₁-C-O-R₂ Meeting in "General"Which statement best describes the first step in the mechanism of the following ether synthesis? Na + CH3I -OCH3 The alkoxide ion acts as a nucleophile and attacks the carbon of the alkyl halide. The alkoxide ion acts as a nucleophile and attacks the iodine of the alkyl halide. The alkoxide ion acts as an electrophile and attacks the iodine of the alkyl halide. The alkoxide ion acts as an electrophile and attacks the carbon of the alkyl halide.3. Which of the following are nucleophiles? 1 CH3NH2 2 CH3O 3 H3CC=CH
- Draw the favored product(s) of the following reactions (organic chemistry)Which atom in the following molecule is considered the electrophilic site, i.e. where would a nucleophile attack? O The O atom in the carbonyl (C=O) group O the Catom in the carbonly (C=O) group O Any H atom O AC atom not in the carbonyl (C=O) groupGive the major substitution product of the following reaction. a O CH3CO₂H Br heat CH₂ ? O There is no reaction under these conditions or the correct product is not listed here.