The reaction illustrated below, when carried out in a non-coordinating solvent, proceeds with high stereospecificity giving mainly a single enantiomer of product (95% enantiomeric excess). Discuss how the reaction is likely to proceed and hence predict both the stereochemistry of the product and the position of the 13C label. 13 CO Ph₂p...Fe OO

The reaction illustrated below, when carried out in a non-coordinating solvent, proceeds with high stereospecificity giving mainly a single enantiomer of product (95% enantiomeric excess). Discuss how the reaction is likely to proceed and hence predict both the stereochemistry of the product and the position of the 13C label. 13 CO Ph₂p...Fe OO

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter9: Nucleophilic Substitution And Β-elimination

Section9.7: Experimental Evidence For E1 And E2 Mechanisms

Problem 9.7P

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