The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4302g sample of CaCO3 was transferred to a 60mL volumetric flask, dissolved using a minimum of 6 M HCl solution, and diluted to volume. A 44mL portion of this solution was transferred into a 250-mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3-NH4 L buffer containing a small amount of Mg2+ EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA, requiring 632mL to reach the end point. Calculate the molar concentration of the titrant

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
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Chapter17: Electrochemistry And Its Applications
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The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4302g sample of CaCO3 was transferred to a 60mL volumetric flask, dissolved using a minimum of 6 M HCl solution, and diluted to volume. A 44mL portion of this solution was transferred into a 250-mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3-NH4 L buffer containing a small amount of Mg2+ EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA, requiring 632mL to reach the end point. Calculate the molar concentration of the titrant 

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