The carbon-carbon bond length of coordinated ethylene in Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal structure analysis. Computational quantum mechanical modelling of the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon- carbon bond length of 1.34 Å for the coordinated ethylene ligand. Rationalise this difference in bond length. Sketch relevant molecular orbitals. (CsMes = pentamethylcyclopentadienyl)
The carbon-carbon bond length of coordinated ethylene in Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal structure analysis. Computational quantum mechanical modelling of the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon- carbon bond length of 1.34 Å for the coordinated ethylene ligand. Rationalise this difference in bond length. Sketch relevant molecular orbitals. (CsMes = pentamethylcyclopentadienyl)
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 116QRT
Related questions
Question
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning