[Standardization] A 0.3045 g of CaCO3 primary standard was dissolved using concentrated HCl, evaporated to incipient dryness and quantitatively transferred to a 250 mL volumetric flask, and diluted to mark. A 10 mL of aliquot was then transferred to an Erlenmeyer flask, together with 5mL buffer and 5 drops of EBT indicator, and was used to standardize the EDTA titrant. The solution turned blue after the addition of 24.10 mL of EDTA. A blank correction was performed and was determined to be 0.4 mL.   What is the concentration of EDTA obtained (MW CaCO3 = 100.0869 g/mol)?

Fundamentals Of Analytical Chemistry
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ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
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Problem 17.35QAP
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[Standardization]

A 0.3045 g of CaCO3 primary standard was dissolved using concentrated HCl, evaporated to incipient dryness and quantitatively transferred to a 250 mL volumetric flask, and diluted to mark. A 10 mL of aliquot was then transferred to an Erlenmeyer flask, together with 5mL buffer and 5 drops of EBT indicator, and was used to standardize the EDTA titrant. The solution turned blue after the addition of 24.10 mL of EDTA. A blank correction was performed and was determined to be 0.4 mL.

 

What is the concentration of EDTA obtained (MW CaCO= 100.0869 g/mol)?

 
  1. 5.050 x 10-3 M

     
  2. 0.1284 M

     
  3. 0.1262 M

     
  4. 5.135 x 10-3 M

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