Provide the missing intermediates and reagentsCHCH2=CH-CH=CH2 (1,4 butadiene) + (1).H.C1. (2)H.C2. (3)H₂CHQH.C(7)(5)+(6) mixture(8)H*H.C(12)(11)ACH₂CH₂H.CCHCH,(4)(5)+(6)mixtureH₂C(10)HOCHH,C(13)2 NaNH,(14)2 CH₂lCH₂

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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What is the organic product formed in the following reaction? NaOC₂H₂ H+(aq) стеносли + OC₂H HOC₂H | -CH₂CH = ||| Select one: A. II B. I C. IV D. III ° -CH₂CH₂ OC₂HS IV -CH OC₂H₂ CH3 OH CH3 O OC₂H₂ bc₂Hs
2) (4pts) Classify each reaction as addition, elimination, substitution, or rearrangement. A) CH;CH2B LIOH CH;CH2OH LiBr B) CH;CH2CH,Cl CH-CH-CH2 + + HCl C) CH;CH=CH2 H2 CH;CH2CH3 Verdana 10pt B IU A v
(a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. AAVIL ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OsO4, H₂O2 On n [ ]#
In the following reaction scheme which products are labeled correctly. 1.) CH(CH) CHO Mg, ether 1-bromobutane 2) H,0+ H,SO, heat KOH, H,O 1) 0z Brz Na 2.) (CHeS/ B CH3CH;CH;CHO | CH;CH;Br CHa(CHzhCHO fused KOH H 1) NANH, 150 C 2.) H:0 1) Sia BH 2.) H,O, NaOHI K 1-попyne 2.) H;O* 2 HBr O The correct structure of C is The correct structure of I is CHO (Sia2BH = The correct structure of F is O The correct structure of K is HO
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8. +) Draw the structure of (2S,3S)-2-chloro-3-methylhexane. Use wedges and dashes (where applicable) to indicate stereochemistry. CI (2S,3S)-2-chloro-3-methylhexane
10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III
5. Consider the synthesis of 2-butanone from butyne: Hg2+ || CH3CH,-C=C–H CH;CH,-Ĉ-CH3 H3o* (iv) Name the class of compound D belongs to. (v) Comment on the stability of compound D compared to 3-butanone.
CH3 to Br- -H + Nal • product; Sy2 product of the reaction is : Аcetone H- -CH3 CH2 – CH3 CH3 CH3 CH3 CH3 it it -H H- -CH3 (d) -CH3 -H- (а) H• (Ъ) H- -CH3 -CH3 (с) H- CH -H- ČH2 – CH3 ČH2 – CH3 CH2 – CH3 CH2- CH3 2.
O (1) H20, H*; (2) Jones reagent (1) H20, H*; (2) PCC, CH2CI2 (1) conc. H2SO4: (2) Jones reagent O (1) H20, H*; (2) Tollens reagent (1) conc. H2SO4: (2) PCC, CH2CI2 O (1) conc. H2SO4: (2) Tollens reagent
6) Provide the major organic product of the following. x 1. Mg, Et₂0 2. CO₂ 3. H₂O* CH₂CH₂ CH₂ O=O Br OCH₂CH3 1. 2 CH₂MgCl 2. H₂O, H* .H 1. CH₂CH₂C=C 2. H₂O, H* ~
II: Complete each of the following reactions by supplying the missing product or reagents: 1. C-CI Н20 + 2. CH3-C- -CH3 + H2O Heat, | OH 2 3. CH3-C- СН3-С— СІ | 4. CH3-CH2-C- -OCH2CH3 H2O H Heat 2 + 5. CH3-CH2-CH2-C-OH + CH3OH HE Heat .?

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Provide the missing intermediates and reagents CH CH2=CH-CH=CH2 (1,4 butadiene) + (1). H.C 1. (2) H.C 2. (3) H₂C HQ H.C (7) (5)+(6) mixture (8) H* H.C (12) (11) A CH₂ CH₂ H.C CH CH, (4) (5)+(6) mixture H₂C (10) HO CH H,C (13) 2 NaNH, (14) 2 CH₂l CH₂