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- Predict 31PNMR spectrum of cis-[Pt(PR3)2Cl2]. Given that phosphorus-31 (100% abundant), platinum-95 (33% abundant), all have a nuclear spin quantum numbers of (I = ½)Answer all of the following about colours and UV-Visible Spectra. a) The very idealized UV-Visible Spectrum of a violet solution of [Sc(H2O)6]** is shown: 3. wavelength A chemist carries out the following reaction: [Sc(H2O)s]* + Z yellow solution [ScZe]* (n depends on Z) Is Za solution of NH3 or a solution of NaBr? Justify your answer. Predict the shift (if any) in the UV-Visible Spectrum for [ScZ6]". Justify your answer. b) The following hydroxide species are all known: Mn(OH)42 Co(OH)4 Zn(OH). • Assign a colour to each species. Possible choices: blue, red, colourless Note: some choices may be used more than once, some not at all. Justify your answer for any one of the species.A solution containing 1.00mg iron (as the thiocyanate complex) in 100mL was observed to transmit 70.0% ofthe incident light compared to an appropriate blank. (a) What is the absorbance of the solution at thiswavelength? (b) What fraction of light would be transmitted by a solution of iron four times as concentrated?
- Predict what you expect to observe in the EPRspectrum of a species in which an unpaired electroninteracts with one 14N nucleus (I = 1) and one 1Hnucleus (I = 1/2) if the hyperfine coupling constantsare (a) A(14N) = A(1H)=30 G; (b) A(14N)= 30 G,A(1H)= 10 G.(a) Draw a block diagram of an atomic absorption spectrometer (AAS). Briefly describe the function of each components. (b) What is the process of atomization in atomic absorption spectrometer? Describe the steps of the process in the correct sequence. (c) State TWO interferences that are encountered in atomic absorption spectrometer. Suggest ONE solution to overcome the problem. (d.) What is the main difference, in terms of instrumentation, between atomic absorption spectrometer and atomic emission spectroscopy?(a) Determine the number and activities of the carbonyl stretching modes of both the cis and trans isomers of L2M(CO)4. (b) Calculate the IR and Raman active carbonyl vibrations for both isomers. (c) Fe(CO)4C12 has IR bands at 2167, 2126 and 1082 cm-1 in CHC13 solution. How would you interpret this spectrum?
- The complex ion [Fe(OH2)6]3+ has an electronic absorption spectrum with a maximum at 700 nm. Estimate a value of Δo for the complex.Lead is determined by atomic absorption at 283.3 nm, whereas it is determined at 405.8 nm by flame emission. Explain why the most sensitive line is different for these two methods.Briefly, but informatively, explain the following as encountered in analytical chemistry: (i) Photoelectric effect (ii) K−absorption edge (iii) Dead time of a detector
- Se(II) has a 3p ground term and a 3d and 3f excited states. (a) how many lines would you expect in the absorption spectrum? (b) how many lines would you expect in our emission spectrum? (c) show the numerical values for all possible S, L, and J This is the only info given, there is no graph.(i) Explain how the mass of the particle(s) involved affects the separation between energy levels in quantum mechanics. (ii) Explain why the sensitivity of an NMR experiment is affected by the strength of the applied magnetic field. (iii) Explain why, to a good approximation, rotational and vibrational transitions do not change the energies of electrons.(A) Calculate the wavelength in nm of an emission line of cadmium with a frequency of 1.311 x 1015 Hz. (B) Calculate the wavenumber in cm-1 of an infrared absorption peak with an associated energy of 5.656 x 10-20 J. Report answers to 4 sig figs