One drop, 0.200 cm3, of 1.00 mol dm-3 of aqueous sodium hydroxide, NaOH, solution is added to 25.0 cm3 of a phosphate buffer that is 0.040 mol dm-3 in KH2PO4(aq) and 0.020 mol dm-3 in K2HPO4(aq). Calculate the resulting pH of the solution given that the second acid dissociation constant, pKa2, for phosphoric acid is 7.21.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section12.3: Determining Equilibrium Constants
Problem 12.3PSP
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One drop, 0.200 cm3, of 1.00 mol dm-3 of aqueous sodium hydroxide, NaOH, solution is added to 25.0 cm3 of a phosphate buffer that is 0.040 mol dm-3 in KH2PO4(aq) and 0.020 mol dm-3 in K2HPO4(aq). Calculate the resulting pH of the solution given that the second acid dissociation constant, pKa2, for phosphoric acid is 7.21.

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