Draw the products formed when benzoyl chloride (C,H;COCI) is treated with each nucleophile: (a) H20, pyridine; (b) CH;CO0"; (c) NH3 (excess); (d) (CHaNH (excess).
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- Draw the products formed when A is treated with each reagent: (a) H2 + Pd-C; (b) mCPBA; (c) PCC; (d) CrO3, H3SO4, H2O; (e) Sharpless reagent with (+)-DET.The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Give the structure corresponding to each name: (a) sec-butyl ethyl ketone; (b) methyl vinyl ketone; (c) p-ethylacetophenone; (d) 3-benzoyl-2-benzylcyclopentanone; (e) 6,6-dimethylcyclohex-2-enone; (f) 3-ethylhex-5-enal.
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) istreated with following reagent. Part (b), then CH3COCl, AlCl3Draw the products of Claisen condensation of (a) ethyl propanoate; (b) ethyl-3-methylbutanoate; (c) ethyl pentanoate. For each, the base used is sodium ethoxide and the solvent is ethanol.Give the IUPAC name for each aldehyde. CH, CH;CHCH-C-H a. CH;CH;CH;-C-CH;CHs сно b. c. (CH):CHCH:CH:CHO d. (CH:).CC(CH):CH:CHO Cire the IUPAC ваше for each ketone/ CH3-C- CHCH2CH3 CH2CH3 ČH3 ČH3
- Draw the product(s) formed when A is treated with each reagent. (a) NaBH4, CH3OH (b) [1] LiAlH4; [2] H2O (c) CH3CH2MgBr; [2] H2OGive the IUPAC name for each aldehyde a. (CH:)2CHCH;CH;CH;CHO b. (CH:);CC(CH:)2CH;CHO CH;CH3 сно c. CH;CHCHCH;CH:CHCH; CH: d. CH3- C-CHCH;CH, е. CH3 CH;CH3 CH3 e. CH3(CH2)4CO2CH; f. CO,CH:CH; g. CH;CH;CH:CH;COOCH:CH2CH;Draw the products formed when A or B is treated with fo following agent. In some cases, no reaction occurs. [1] LiAlH4; [2] H2O
- Draw the products formed when A and B are treated with each of the following reagents: (a) Br2, FeBr3; (b) HNO3, H2SO4; (c) CH3CH2COCl, AlCl3.Problem 15 of 44 68 Draw the major product of this reaction. Ignore inorganic byproducts. TSOH, CH3CH2OH (2 equiv) Submit Assume that the water side product is continuously removed to drive the reaction toward products. Select to DrawDraw the products formed when phenol (C6H5OH) is treated with each set of reagents.a. [1] HNO3, H2SO4; [2] Sn, HCIb. [1] (CH3CH2)2CHCOCI, AlCl3; [2] Zn(Hg), HCIc. [1] CH3CH2CI, AlCl3; [2] Br2, hvd. [1] (CH3)2CHCI, AlCl3; [2] KMnO4