Draw the most likely ion fragment for the signals at m/z 111, 139, and 156.

World of Chemistry, 3rd edition
3rd Edition
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Chapter6: Chemical Composition
Section: Chapter Questions
Problem 6STP
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Draw the most likely ion fragment for the signals at m/z 111, 139, and 156.

The mass spectrum of Compound E is shown below.
100
m/z
Keamatan
Intensity
21.3
75.0
76.0
77.0
6.8
3.0
2.5
1.9
1.0
1.0
32.5
3.7
11.3
1.0
100.0
10.5
38.1
3.6
80
85.0
104.0
105.0
110.0
111.0
112.0
60
113.0
114.0
139.0
140.0
141.0
142.0
149.0
156.0
158.0
184.0
186.0
40
1.4
21.2
7.7
20
7.3
2.2
[M]*
C9H9CIO2
25
50
75
100
125
150
175
m/z
Reative
htensity
O5 9 O O57 30O5 164N732
Transcribed Image Text:The mass spectrum of Compound E is shown below. 100 m/z Keamatan Intensity 21.3 75.0 76.0 77.0 6.8 3.0 2.5 1.9 1.0 1.0 32.5 3.7 11.3 1.0 100.0 10.5 38.1 3.6 80 85.0 104.0 105.0 110.0 111.0 112.0 60 113.0 114.0 139.0 140.0 141.0 142.0 149.0 156.0 158.0 184.0 186.0 40 1.4 21.2 7.7 20 7.3 2.2 [M]* C9H9CIO2 25 50 75 100 125 150 175 m/z Reative htensity O5 9 O O57 30O5 164N732
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