Derive the integrated form of a third-order rate law v = kr[A] 2 [B] in which the stoichiometry is 2 A + B −−→ P and the reactants are initially present in (a) their stoichiometric proportions, (b) with B present initially in twice the amount.

Derive the integrated form of a third-order rate law v = kr[A] 2 [B] in which the stoichiometry is 2 A + B −−→ P and the reactants are initially present in (a) their stoichiometric proportions, (b) with B present initially in twice the amount.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section: Chapter Questions

Problem 113QRT

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Question

Derive the integrated form of a third-order rate law v = kr[A]
2
[B] in which the stoichiometry is 2 A +
B −−→ P and the reactants are initially present in (a) their stoichiometric proportions, (b) with B
present initially in twice the amount.

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