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- 4. Draw the most and least stable conformations of the following substituted cyclohexanes in the chair format (excluding transient conformations like half chair, twist boat and boat). Br BL Br Br5) Use compounds X, Y and Z (shown below) to answer the following questions. H. H3C" "CH3 ОН CH3 compound X compound Y compound Z a) Is compound X classified as cis, trans or neither? b) Is compound Y classified as E, Z or neither? c) Is compound Z classified as R, S or neither? d) Are compounds X and Y constitutional isomers of each other? (YES or NO) e) Are compounds Y and Z constitutional isomers of each other? (YES or NO) f) Classify compound Y as a primary, secondary or tertiary alcohol. g) Which compound(s) is(are) chiral? h) Give the IUPAC name for compound Z, omitting the absolute configuration (R or S) designation. i) In the indicated spaces below, draw stereoisomers of compounds X, Y and Z. stereoisomer of compound X stereoisomer of compound Y stereoisomer of compound Z7. Determine the major product of the reaction. CH3 CH3-CH=ċ-CH, + HBr a) CH3 b) CH3 CH,Br-CH=ċ-CH3 CH;-CH2-CH-CH3 CH3 CH3 c) CH;- CH -ČH– CH, d) CH3-CH,-Ċ-CH; Br Br
- Dehydration of 1,2,2-trimethylcyclohexanol with H2SO4 affords 1-tert-butylcyclopentene as a minor product. (a) Draw a stepwise mechanism that shows how this alkene is formed. (b) Draw other alkenes formed in this dehydration. At least one must contain a five-membered ring.Draw the skeletal structure of a neutral acyclic molecule with one tetrahedral stereocenter. You may use only 8 carbon atoms and 1 halogen atom, plus as many hydrogen atoms as you like. Click and drag to start drawing a structure. S Shm C16. Which of the following is the most stable carbocation? a) *CH3 b) CH;CH,* c) (CH3),CH* d) (CH;);C*
- Using the cyclohexane with the C’s numbered as shown, draw a chair form that ts each description.a. The ring has an axial CH3 group at C1 and an equatorial OH on C2.b. The ring has an equatorial CH3 group on C6 and an axial OH group on C4.c. The ring has equatorial OH groups on C1, C2, and C5.Glucose is a simple sugar with five substituents bonded to a sixmembered ring. a.) Using a chair representation, draw the most stable arrangement of these substituents on the six-membered ring.b.) Convert this representation to one that uses a hexagon with wedges and dashed wedges.c.) Draw a constitutional isomer of glucose.d.) Draw a stereoisomer that has an axial OH group on one carbon2. H,N но PE PC In order to synthesize PC from PE, PE is reacted with three S-adenosylmethionine (SAM) molecules, producing three S-adenosylhomoserines (SAH). Draw the chemical reactions leading from PE to PC, including the important intermediates. Use the arrow formalism. Feel free to abbreviate certain groups with R to avoid excessive drawing, but make sure to draw the full substrates and products with all atoms at least once. H2N H2N N- он он N' NH2 NH2 KH Нон он OH OH S-adenosylmethioning S-adenosylhomoserine
- Using the cyclohexane with the C's numbered as shown, draw a chair form that fits each description. a.) The ring has an axial CH3 group at C1 and an equatorial OH on C2.b.) The ring has an equatorial CH3 group on C6 and an axial OH group on C4.c.) The ring has equatorial OH groups on C1, C2, and C5.Draw product F. Select Draw C (C3H5)3P*-CH23) Draw a cyclohexane chair with 3 substituents in the most stable conformation. Explain why the conformation you've chosen is the most stable.