(b) An organic compound (A), having MF CgH12O reduces Fehling solution and Tollens reagent. The prominent peaks at m/e = 100, 71, 58, 44, 41 and 29 are observed in its mass spectrum. What will be probable structure of the compound? %3D

(b) An organic compound (A), having MF CgH12O reduces Fehling solution and Tollens reagent. The prominent peaks at m/e = 100, 71, 58, 44, 41 and 29 are observed in its mass spectrum. What will be probable structure of the compound? %3D

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.29P

See similar textbooks

Related questions

Q: Structural formula with bond polarity for HCL

A: An ionic bond is formed by complete transfer of electrons from one atom to another A covalent bond…

Q: Calculate the ΔH for the reaction. Show the complete and step by step solution. NO(g) + O(g) -> NO2…

Q: How can you tell if a certain reaction shows an increase in entropy? a) If the reactant is in…

Q: AG° 'cell 1 > 0 1 1

A: From the relationship, □G° = -nFE° = -RT×ln(K)

Q: 20.00 mL of 0.0750 M benzoic acid ( C6H5COOH) is titrated with 0.0250 M NaOH. Ka benzoic acid = 6.5…

A: Given, [C6H5COOH] = 0.0750 M Volume of C6H5COOH in mL = 20.00 mL [NaOH] = 0.0250 M Acid…

Q: What is the mole fraction of ethanol of an aqueous solution that is 20% ethanol?

A: Given : Ethanol = 20%

Q: Qi: Classify if the following reactions are redox reactions. For each of the redox reaction…

A: Note : Since you have posted multiple questions, we are entitled to answer the first only. Please…

Q: In the reaction at equilibrium: 2NH3 (g) ⇌ N2(g) + 3H2(g), Le Chatelier's principle predicts that if…

A: The equilibrium reaction given is, => 2 NH3 (g) ⇌ N2 (g) + 3 H2 (g) Given: If moles of H2 is…

Q: (b) Identify the indicated entiotopic/diastereotopic/homotopic magnetically equivalent or…

A: Homotopic : One of hydrogen is replaced by chlorine gives one compound. Other hydrogen atom is…

Q: Chemistry What is the correct curved arrow mechanism to get from the starting material to the…

Q: Write a Lewis structure that obeys the octet rule for OCSOCS and assign formal charges to each atom.…

Q: 2. Calculate [HT]e, if 12.1 ml of 0.120 M N2OH was required to titrate 25.0 ml of the KHT in pure…

Q: Calculate the ksp for this hypothetical an ionic compound M2X3 (MM=288 g) if its solubility is 3.6…

Q: 3. Balance the reaction and then answer the following question: NaOH + H2S04 → H20 + Na2S04 a. How…

A: 1 mole = 6.022×1023 (Avogadro's number) The mass of one mole of molecules of a substance is called…

Q: How many grams of silver chloride are produced from 5.0 g of barium chloride reacting with an excess…

A: The balance chemical reaction : 2AgNO3 + BaCl2 ----> 2AgCl + Ba(NO3)2 Mass of barium chloride =…

Q: The scientist who first proposed the order of electron distribution within subshells was _______.…

Q: You weigh a dry flask, and place a chunk of solid into it. then weigh it again. You then fill the…

Q: Litmus paper is commonly used to determine if a solution is acidic or basic. Which of the following…

A: To identify: Correct statement about litmus paper.

Q: hat are all the possible resonance structures for the following ions or molecules: nitrate ion, form

A: Given : We have to draw the resonating structures for the nitrate ion.

Q: An ionic compound with the formula Q,Z has a molar solubility of 2.70 x 102 M. What is the value of…

A: Given: Molar solubility of Q2Z = 2.70 × 10-2 M

Q: Which of the following compounds is optically active? Select one: a. CI- CI Ob. CI CI o d. All of…

A: if the molecule cut into two halfs nothing but plane of symmetry then that molecule is achiral…

Q: Draw a structural formula for the major organic product of the reaction shown. CHCH3 HBr + • You do…

Q: Identify the significant functional groups and interpret/ describe the FTIR spectrum for the solid…

A: A question based on IR spectroscopy that is to be accomplished.

Q: Calculate the molar concentration barium hydroxide solution if it was standardized against 0.1112…

Q: 33. A solution was made by dissolving 2 g of a solute in 100 g of acetone. The solution boiled at…

Q: An EDTA solution was prepared by dissolving approximately 4.0 g of disodium salt in approximately 1…

A: The concentration terms explains the mass of solute present in the total volume of the solution.…

Q: 0.121M HClO4 [H+] [OH-] PH pOH

A: Given-> Molarity or concentration of HClO4 = 0.121 M

Q: Write the rate law for the decomposition of ammonium nitrite into nitrogen gas and water using the…

Q: A 22.4 L sample of nitrogen at 3.65 ATM and 22 degree C is simultaneously expanded to 57.4 L and…

Q: . How much heat is gained by copper when 51.8 g of copper is warmed from 15.5°C to 76.4°C? The…

A: Given :- mass of Cu (m) = 51.8 g Specific heat of Cu (c) = 0.385 J/(g.°C) Initial temperature (T1)…

Q: If you titrate 25.00 mL of 0.05 M NaOH with 0.025 M HCl, a.what is the hydronium ion concentration…

A: Given: Concentration of NaOH = 0.05 M Volume of NaOH solution = 25.00 mL = 0.025 L…

Q: Give two examples of the Personal Error (one of the classification of systematic error). Please do…

A: Personal errors are types of operational errors that arise due to personal limitations of the person…

Q: Human milk contains the oligosaccharide 2′-fucosyllactose…

A: Human milk contains the oligosaccharide 2′-fucosyllactose…

Q: those that do hydrogen bond, draw a diagram of two molecules using a dotted line to indicate where…

Q: ने ड.न० तोा oरी कबबक डि अकलबकदल it25.00 me vimegुa ड अकनबनटल to नमह एदपांपवोलत्e Paोकर्व पयंने…

Q: A. 8B. Which molecule is hydrolyzed most slowly with aqueous NaOH? D. C. В.

A: Given compounds are :

Q: Hemoglobin is an important biological molecule in red blood cells. The roll of hemoglobin is to…

A: Since you have posted a question with multiple sub-parts, we will solve the first three subparts for…

Q: Which contributes to the π aromatic system?

Q: Give two examples of the offset errors

A: Offset error arises due to the initial point is not calibrated to zero.

Q: A dissociated strong acid is normally present in an aqueous state as HA. True False

Q: QUESTION 5 Which of the following reactions forms the product shown as the principal product? There…

Q: 1. How many grams of Ca(OH)2 are needed to neutralize 25.0mL of .100M HN03? The reaction proceeds as…

Q: Give the concentrations and tell whether the solution is an acid or base. 1.[H+]=1.0 X 10^-1 M…

A: In this question we have to tell that solution is acidic or basic depending upon value of PH.

Q: Pt(s) | H,(g, 0.839 atm) | H*(aq, ? M) || Cd²+(aq, 1.00 M) | Cd(s) balanced reduction half-reactions…

A: Given : We have to calculate concentration of hydronium ion.

Q: Phosphorus-32 is a commonly used radioactive nuclide in biochemical research, particularly in…

Q: If enthalpy is +220 kJ for a reaction and entropy is +120 J, at what temperature is this…

A: The spontaniety of any reaction is decided by the Gibb's free energy change if the reaction. Any…

Q: The pH of a solution that is 0.5 in MA and 0.3 in HA is 5.40; determine the pKa of the acid.

Q: (b) An organic compound (A), having MF C,H120 reduces Fehling solution and Tollens reagent. The…

A: Compound A reduces the Tollens reagent. Therefore the compound is having aldehyde FG. Therefore the…

Q: 4. The anisole derivative below undergoes a selective cross coupling reaction on only one of the two…

Q: Please answer both the structure otherwise I'll downvote

A: Given structures are : a). b). What are the IUPAC names of the given compounds = ?

Concept explainers

Analyzing and Predicting Spectroscopic Data

The interaction of electromagnetic radiation with the structure of molecules in the sample and their study is referred spectroscopy. Several spectroscopic methods are used to acquire sample information, and these methods are proved to be accurate, fast, and non-destructive. The information obtained about the content and composition of molecules from these spectroscopic methods is called spectroscopic data.

Question

100%

Pls solve this problem and I upvote and pray for your wellbeing

(b) An organic compound (A), having MF CH120 reduces
Fehling solution and Tollens reagent. The prominent peaks
at m/e = 100, 71, 58, 44, 41 and 29 are observed in its mass
spectrum. What will be probable structure of the
compound?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Given

VIEW

Answer

VIEW

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Analyzing and Predicting Spectroscopic Data

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

How could 1H NMR spectroscopy be used to distinguish among isomersA, B, and C?
13. (a) A compound with molecular formula С -HаО exhibited m/z 108, 93, 78, 77, Derive the most probable 65, 51. structure.
(b) Determine the structure of an organic compound with a molecular ion at m/z 73 and absorption in its IR at 3300 (doublet) and 1680 cm
2,3-Dimethylbutane and 2,2-dimethylbutane have the same molecular ion in the mass spectrum, but only one of these isomers gives a significant fragment at m/z = 57. (a) Which isomer shows an intense peak at m/z = 57? (b) Propose a structure for the ion that gives rise to this peak. (c) The base peak in the mass spectrum of the other isomer occurs at m/z = 43. What ion gives rise to this peak?
For the following molecules, indicate whether the hydrogens marked Ha and Hh are homotopic, enantiotopic or diastereotopic and give a reason for your . answer. (i) (ii) (iii) CH,Br На CH,Br CH,Br На H;CH,C V'Ha Hb Hb Hb
Predict the masses and the structures of the most abundant fragments observed in the mass spectra of the followingcompounds.(a) 2-methylpentane (b) 3-methylhex-2-ene (c) 4-methylpentan-2-ol(d) 2-methyl-1-phenylpropane
Treatment of anisole (CH3OC6H5) with Cl2 and FeCl3 forms P, which has peaks in its mass spectrum at m/z = 142 (M), 144 (M + 2), 129, and 127. P has absorptions in its IR spectrum at 3096–2837 (several peaks), 1582, and 1494 cm-1. Propose possible structures for P.
Predict the masses and the structures of the most abundant fragments observed in the mass spectra of the followingcompounds.(a) 2-methylpentane (b) 3-methylhex-2-ene (c) 4-methylpentan-2-ol(d) 2-methyl-1-phenylpropane (e) cyclohexyl isopropyl ether [cyclohexyl¬O¬CH(CH3)2](f) CH3CH2CH2NHC(CH3)3tert@butyl propyl amine(g) C CH3Oacetophenone(g) *(h) 3-bromo-2-methylpentane
(a) What mass spectral fragments are formed by a cleavage of butan-2-ol, CH3CH(OH)CH2CH3?(b) What fragments are formed by dehydration of butan-2-ol?
) Predict the probable structure of a compound with formula Cl,Mn,C;Og, where the spectrum included mass prominent peaks at m /z= 404, 376, 348, 320, 298, 264, 236, 208, 180, 110 and 55 a.m.u. %3D
G.5 Mass spectra were acquired for 1,4-diethylbenzene and 1-methyl-4- propylbenzene. The base peak of spectrum A is at m/z = 105 and that of spectrum B is at mlz = 119. Match each spectrum to its compound.
Q1. How will you distinguish the two members of each of the following pairs of compounds using IR spectroscopy: (a) CH;COOH and HCOOCH; (b) B-propiolactone and y-butyrolactone (c) CICH,CH,CH;COOH and CH;OCH,CH,COCI (d) CH,CH,CHO and CH,=CH-CH,OH please explain each clearly