Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or aleohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two in-plane bonds per cach chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. Be sure to draw hydrogens on oxygen, where applicable. Select Rings More Draw Erase 1. B2H6, diglyme 2. H2O2, HO-, The product or products of the reaction are characterized as being racemic. achiral. R,S (and/or S,R). R. S,S. R.R. diastereomers.

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Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols
formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two
O Hint
in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b)
Characterize the product or products of the reactions.
The first step of the reaction,
hydroboration, involves addition of
BH, to the double bond, with -BH,
attached to one carbon and hydrogen
Be sure to draw hydrogens on oxygen, where applicable.
attached to the other. Consider both
Rings
the regioselectivity and the
Select
Draw
More
Erase
stereochemistry of this addition.
H
Diborane, B,H,, is a source of
borane, BH,, and can be used
1. B2H6,
interchangeably. Diglyme is
a solvent.
diglyme
2. H2О2, НО",
The product or products of the reaction are characterized as being
O S.
O racemic.
O achiral.
O R,S (and/or S,R).
O R.
O S,S.
O R.R.
O diastereomers.
Transcribed Image Text:Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two O Hint in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. The first step of the reaction, hydroboration, involves addition of BH, to the double bond, with -BH, attached to one carbon and hydrogen Be sure to draw hydrogens on oxygen, where applicable. attached to the other. Consider both Rings the regioselectivity and the Select Draw More Erase stereochemistry of this addition. H Diborane, B,H,, is a source of borane, BH,, and can be used 1. B2H6, interchangeably. Diglyme is a solvent. diglyme 2. H2О2, НО", The product or products of the reaction are characterized as being O S. O racemic. O achiral. O R,S (and/or S,R). O R. O S,S. O R.R. O diastereomers.
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