- Aktiv Chemistry ← → C M Gmail b Answered: Draw the major pro × | + app.aktiv.com ☑ ੩ ॥ YouTube Uconn G Google rent research American Red Cro... Duty Officer Home Redcross email Duty Officer |... Fight or Flight Em... Problem 1 of 10 Draw the enolate anion and the carbonyl that would be needed to make this product through an aldol condensation reaction. H Draw Enolate Anion + Please select a drawing or reagent from the question area > B Relaunch to update : All Bookmarks Submit
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- resource from Cengage Learning - Google Chrome ssignment/takeCovalentActivity.do?locator=assignment-take e by the Aldol Condensation (References) OH base + H,0 heat H. H3C H. The aldol reaction is a carbonyl condensation reaction between two carbonyl partners and involves a combination of nucleophilic addition and a-substitution steps. One partner is converted into an enolate ion nucleophile and adds to the electrophilic carbonyl group of the second partner. In the classic aldol reaction, the carbonyl partners are aldehydes or ketones, although aldehydes are more reactive. The product is a B-hydroxy carbonyl compound. In the mixed aldol reaction, the best results are obtained when one of the partners does not have an a-hydrogen. It cannot form an enolate anion and can therefore not undergo self-reaction. The enolizable aldehyde is added slowly to a basic solution of the first aldehyde so that the mixed product is preferentially formed. Under reaction conditions slightly more vigorous…MacBook Air Page |3 6. Give the complete mechanism for the following reaction. MgBr 1. 2. H,0* od of sluuslom anie b Aom ua (co (ogami 1omim ai ao sldasog cobo 7. Show the complete mechanism for the formation of a hemiactetal, when 3-methyl-2-butanone reacts with ethanol under acidic conditions (H2SO4).The answer to this question is D, can you please draw the mechanism to get that product? 1. -MgBr H;0* workup ? OTMS 2. TBAF 3. POCI, / pyridine (еxcess) 4. Нeat он A B он CI CI D
- 15. Predict the product for the following reaction and 16. provide a stepwise, curved arrow, mechanism for the formation of the product. CH3OH H₂SO4 || = ||| IV ABCD A. B. C. Which of the following reactions would not yield propyl butanoate as major product? ===> OH NH₂ LOH H₂SO4 OH pyridine OH OH H₂SO4The following reaction should under go a(n) H₂C SN1 Br NaSPh DMF A/ reaction.Please pronde ne approprate reagents or product. 1.Os0y,TBHP, H20/THF -> 2. TSOH, acetone, PhH,neat 3. AICI3, CH3COCI, CH2C12 2) 1. B200B2,NBS, CC14> 2. Mg, THF;then Pa°Ln, PhBr 3. HNO3 , HzSo4 4. 2n, HCI me Br Me0 (3 meo MeN HN Meo me Br
- Draw the final organic product of the following three-step reaction of bromomethylbenzene. Br 1. NaCN 2. CH3MgBr 3. H3O*, H₂O Select Draw / ||| ||| Templates с H More N Erase Q2 QBu Br ML. से 1) 1.05 nBuLi 2) A) -78 30 min MeOH B-78 to RT for 1h; MeOH e Bu H what would be the mechanism/interaction between the n-Butyllithium and the starting material to get to the product? Please explain step by step.26. Which energy profile corresponds to the mechanistic pathway for this reaction? LOH H* 3 (C) (A) Energy->> (C) Energy-> ли Reaction Coordinate my Reaction Coordinate HO (B) OH @ (B) Energy->>> (D) 27. What is the major product of this reaction sequence? 1. NaNH2 2. Br 3. HgSO4, H₂SO4, H₂O 4. 5. H₂O + H₂0 M nm Reaction Coordinate mi Reaction Coordinate OH
- + II HI Identify the MAJOR product that would be obtained at the end of the following reaction sequence. (i.e. the final product not the "isolated intermediate") 3. 9. NaNH2 then isolated intermediate HCI excess CI ci Rain showers 1. 2 #3 3. 2$ 4. 114 A 5 E. %23 PrtScn INE Sn R. & 9. Home 7. 61 08. PgUp 6. Alt su K P. B. Backsp 7. Alt 目1NODET room teme 2. CH3 CH2B (1 equi)" Enolate Anion + Katone Aldehyde OH 1. NAOH 2.neut wokup Enolate + Esteu Electrophiile CH3ONA, CH30H 1.CH3CH2)2NH, pH 4-5 2. CHCH2 CHO 3. H30+ OH starting1. Provide structures for the products and/or starting materials for the following reactions. Donor Acceptor NaOH CH₂CH₂OH heat loss of H₂O H3C mixed-aldol condensation product NaOH CH₂OH heat *) NOE EtOH #40 2) H₂O* ΕΙΟ CH₂ mixed-Claisen condensation product +HgC. H3C CHS H loss of H₂O mixed-aldol condensation product H3C людете CH3 NaOEt loss of H₂O intramolecular aldol condenstation cyclization product