About the special type of hybridization involved in complexation (all are correct except Select one: 1- in case of d2sp3 hybridization trigonal (square planner) shape complex is obtained while in case of dsp2 hybridization a hexagonal shape complex is obtained

Q: Use ligand group orbital approach to describe the bonding in [CO3] 2- . Include schematic…

A: Carbonates [CO3] 2-are polyatomic ligands. They are found to bind to two or three metals…

Q: or False: direction of the ligand p orbitals considered to form sigma bonds Pz ue

A: For the sigma bond formation between p orbitals, the pz orbitals will face to face over lap.

Q: (a) Sketch the molecular orbitals of the H2- ion and draw itsenergy-level diagram. (b) Write the…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: How can a molecular orbital diagram predict the energy of the d-orbital splitting (using the σ…

A: The MOT of the octahedral complex in the presence of different donor ligands are given below:

Q: Predict the structure of I(CF3)Cl2. Do you expect the CF3 group to be in an axial or equatorial…

A: Generally the groups which are more electronegative will occupy the axial position while depicting…

Q: Q3. Draw the d-orbital splitting diagrams of the central metal ions in a. Heptacyanoosmate(IV) b.…

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Q: 1). Which d-orbitals become t, orbitals according to the character table below? Character table for…

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Q: Use resonance forms to show that the dipolar sigma complex shown in the sulfonationof benzene has…

A: The resoanace forms which shows that the dipolar sigma complex in the sulfonation of benzene…

Q: (a) prepare a molecular orbita; energy level diagram for the cyanide ion, CN-.  (b) What is the…

A: All the solution  explained  in Handwritten  solution.  Carbon is less electronegative  than…

Q: b. Explain in molecular orbital terms the changes in H-H inter-nuclear distance that occurs as the…

A: Bond Order is the number of bonding electron pairs between any two atoms.

Q: 2. Draw the structure of borazine and identify its symmetry elementals and operations

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Q: Here is a portion of the MO diagram for a particular molecule. Atomic orbitals are labeled with…

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Q: =c= N: H - C= N: N: CN32- FCN HCN OCN

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Q: Which of the following molecule(s) belong to CooV point group? 1. CO 2. H2 3. HCI 4. 02 * O 1 and 3…

A: We have to ask which of the molecule belong to C∞V point Group  1. CO   2. H2     3. HCl    4. O2…

Q: Select the metal centre with d2sp3 hybridization. a.[Rh(acac)3] b.[RuMe2(bpy)2] c.[RhCl3(PMe3)]…

A: The above problem can be solved using the valancy bond theory.  Which states about strong field and…

Q: Sodium fluoride exists as a molecule in the gas phase under high tèmperature and vacuum conditions.…

A: We know that, Molecular formula of Sodium Fluoride is NaF Hence, For the MO Diagram for NaF, we need…

Q: NiCl4]2- and Ni(CO)4 have sp3 or dsp2 hybridization? Explain. What type of hybridization is shown by…

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Q: Question attached

A: ANSWER : first we have to count the total no. of valence electrons in  SN-    electronic…

Q: The major component of household bleach is sodium hypochlorite. In South Africa, bleaching solution…

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Q: Bro 1) The orbital potential energies for the 4s and 4p of Br are -18.65 ev and -12.49ev,…

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Q: The following sketches show the atomic orbital wave functions(with phases) used to construct some of…

A: (a) s and s atomic orbitals forming σ MO

Q: Which one of the following is correct regarding the symmetry of molecular orbitals? O Td is g O Od…

A: g means gerade Sigma bond always forms gerade.

Q: Q3 a) Calculate the CFSE for the following ions in an octahedral field: Cr2*, Co2*, Mn²+ and Zn²+ ?…

A: CFSE = Crystal Field Stabilization Energy All given metals belongs to 3-d period d orbitals energy…

Q: Draw the Lewis structures and molecular orbital (MO) diagrams for CO and CN and comment on both the…

A: In lewis dot structure molecules or compounds are represented by bonding and non bonding electrons…

Q: The orbital potential energies for the 4s and 4p of Br are -18.65 ev and -12.49 ev, respectively.…

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Q: XeF4 was the first binary compound of a noble gas that was synthesized. It is a square planar…

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Q: Based on the shapes of p and d orbitals and the necessary match of symmetry, please predict and…

A: Atom A orbitals - p Atom B orbitals - d We have to draw the possible bonding interactions between A…

Q: To answer the next several questions, sketch the MO diagrams for the following molecules: 02. 022+,…

A: According to the molecular orbital theory, the atomic orbitals combine to forms molecular orbitals.…

Q: Moleaular orbital (MO) theory relates to the symmetry properties & relative energies of atomic…

A: Molecular orbitals are formed when the atomic orbitals with nearly or equal energy are overlapped…

Q: Formulate the MO structure of (NO;) for localized o bonds and de-localized 7 bonds. Is it linear or…

A: The NO2+ molecular ion has 16 valence electrons (five from nitrogen atom, six from oxygen atom). For…

Q: The azide ion ( N3-) is a weakly bound molecular ion. Formulate its MO structure for localized s…

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Q: a) Draw the open structure of BH2ÇI. (At. No of B: 5) b) Predict the symmetry species of IR…

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Q: 10. H,S is one of nature's most foul smelling substances and it has H-S-H bond angles of very close…

A: Since you have posted multiple questions, we will answer only first question for you. If you want…

Q: In ozone, O3, has a central atom, O (it is not shaped like an equilateral triangle). Create a Mo…

A: Given:-  In ozone, O3, has a central atom, 0 (it is not shaped like an equilateral triangle). To…

Q: Q2 a) Calculate the CFSE for the following ions in an octahedral field: Cr2*, Co2*, Mn²+ and Zn²+ ?…

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Q: Indicate the symmetry of the following orbitals: a) Fluorine px orbitals of OF2. b) Fluorine pz…

A: symmetry element : it is the element or the point around which all the operations of symmetry takes…

Q: Which one of the following is correct regarding the symmetry of molecular orbitals? O Tg is g O Od…

A: "g"  and  "u"  Stands for the gerade and ungerade respectively. These are symmetry of molecular…

Q: Draw the hybridization for the metal centre of the complex below

A: According to Valence bond theory: Electrons in a molecule occupy atomic orbitals rather than…

Q: Prepare molecular orbital energy-level diagrams for C22-. Label the orbital type (e.g. o, n*,…

A: C22- Atomic number of C = 6 Electronic configuration = 1s2 2s2 2p2 Total electrons in C2 = 12 Total…

Q: Using a group theory approach and the CO bond vectors as your basis determine if MnCl(CO)5 is…

A: The point group of MnCl(CO)5 is C4V.The character table of C4V is given below.

Q: 1. Where are the symmetrical classifcations on the molecules? 2. What is the point group for each…

A: Following are the symmetrical classification, point group and chirality of the given compounds.

Q: Sketch the MO diagram for 1,3 butadiene

A: Draw MO diagram of 1,3 butadiene ?

Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.