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- aw the products for the following reactions showing the formation of amides. Name the 5. reactants and the products. CH Nit + Ho- Cat b) CH-CH NH looc Cat. oH -WH looc cat 6. Draw the products when each of the amides undergoes acid hydrolysis. Name the reactants and products. HCL Cty- -NH-C_Cy+ 0 HCL b) C-CH-N-&cnycy +4,0 HCL + H,0 digCOOH 100 Amide tO NHCH1. Lit :E 2. HCI Br2, H20 Isunepe enc toss1gwolol ert to rlose 107 (2nion S bonsdmun ed bluorde yisaeesen li ele bensdr CI 18 LICH3 HO 1emonsne+ CI H. (MCPBA) rt ol egete bns ainepssonitail elesrinye biewiols s2ogon9 (niog E E eluoslom e pelom CH3OH catalytic H2SO4
- 30 COOH (1) 2 CH3CH₂Li (2) H3O+ H3O+ C=PPh3 H я ↑ CH3 NH2 H+, heat (lose H₂O)Draw the organic product(s) for each of the following reactions. If there is more than one product likely indicate the major. Be sure and show any stereochemistry.y 10-Whic.g ne yo1owing compounds is theigtrongest base |(circle your angwers? wnicn Of the foilow ing compounds in the strongegt basl (circle your anower)? THN NH2 12. which Of the following compounds Possesses a 3° amine (crce all possible angwerg) ? NH
- Arrange the following compounds in decreasing order of acidity * |- CICH2CH2CH2COOH Il - CH3CH2CHCICOOH III – CH3CHCICH2COOH III > I> || O I > II > || O I > I| > II III > || >|Determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products:(a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.Using the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.