26) Consider the following elementary steps. What is the overall reaction? A + B C C + B k₁ K-1 k₂ + D D Step 1: (fast) Step 2: (slow)

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 22P
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26) Consider the following elementary steps. What is the overall reaction?
A + B C
C + B
k₁
K-1
k₂
+ D
D
Step 1: (fast)
Step 2: (slow)
Transcribed Image Text:26) Consider the following elementary steps. What is the overall reaction? A + B C C + B k₁ K-1 k₂ + D D Step 1: (fast) Step 2: (slow)
29) The overall rate law for problem 26 is
Rate = K₂k-1 [A[B]D]²
k₁
a) Rate
_k₂k₁ [A[B]D]
k_₁
-1
c) Rate = k₂ [A[B][D]¹
d) Rate
_k₂k₁ [A][B][D] ¹
k_₁
b) Rate =
e) Rate = k₂ [AIBID]¹
Transcribed Image Text:29) The overall rate law for problem 26 is Rate = K₂k-1 [A[B]D]² k₁ a) Rate _k₂k₁ [A[B]D] k_₁ -1 c) Rate = k₂ [A[B][D]¹ d) Rate _k₂k₁ [A][B][D] ¹ k_₁ b) Rate = e) Rate = k₂ [AIBID]¹
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