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- 1. Describe the following reactions of amines, include equations if possible a. Hinsberg reactionb. DiazotisationList at least three (3) physical or spectroscopic methods that can be used to differentiate between benzophenone and benzhydrol. Explain how you would differentiate them.What reagents would you use to chemically extract benzoic acid and valeric acid? Or can it not be chemically extracted? The image shows the compound structure.
- Analyze the synthesis problems of Isopropylamine can be prepared by reduction of nitro compound,but cannot be prepared by reduction of a nitrile,even though it is primary amine1. Arrange the test samples in order of increasing reactivity with sodium bicarbonate? Explain briefly -Ethanoic acid, Butanoic acid, Benzoic acid 2. Arrange the test samples in order of increasing solubility in water? Explain briefly. -Ethylamine, Diethylamine, Aniline 3. Arrange the test samples in order of increasing basicity? Explain briefly. -NaOH, Ethylamine, Aniline1. Why can a NaOH be used to distinguish amide and ammonium salts? Multiple choice2. In the synthesis of gabriel, phthlamide acts as? Explain(a) Catalyst(b) Reagents(c) Nucleophile(d) Electrophic 3. Amine compounds that can fade the color of the bromine solution, namely?
- C) a nitrile D) an amine nitrite salt DIRECTIONS: Each of the following questions or incomplete statements below is followed by four suggested answers lettered A - D. Select or choose the letters of the best answer to the question or incomplete statement. 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acid Which one of the following reagents reacts 1. in a similar fashion with both phenylamine (C H,NH,) and ethylamine. A) Br,(aq) C) conc. HNO, D) cold HNO (aq) 2. Phenylamine (aniline) can be prepared by reducing nitrobenzene with tin and concerntrated hydrochloric acid followed by the addition of alkali and finally steam distillation. The alkali is added to; A) prevent oxidation of phenylamine. B) liberate free phenylamine from solution C) dissolve excess nitro benzene D) dissolve the phenylamine 8. Arrange the following molecules in their increasing order of base…6. The reaction between aniline and nitrous acid at low temperature yields A) an N-nitroso amine B) a diazonium salt C) a nitrile D) an amine nitrite salt 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acidThe gas-phase basicity of triphenylamine (876.4 kJ mol-1) is less thanthat of triphenylphosphine (940.4 kJ mol-1). Write an equation torepresent each reaction. Do you expect electronic or steric factors tocontribute more to this difference? Explain
