Answered: 2. The first ionization energy of neon… | bartleby

Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter2: Atomic Structure And Periodicity

Section: Chapter Questions

Problem 33Q

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Question

2. The first ionization energy of neon (2.08 MJ/mole) is determined by photoelectron spectroscopy
(PES). Calculate the wave number (v) of incident radiation in order to generate photoelectrons
with de Broglie wavelength (e) equal to 2.34×10-10 m.

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Cesium was discovered in natural mineral waters in 1860 by R. W. Bunsen and G. R. Kirchhoff, using the spectroscope they invented in 1859. The name came from the Latin caesius ("sky blue") because of the prominent blue line observed for this element at 455.5 nm. Calculate the frequency and energy of a photon of this light.
Spectroscopists have observed He+ in outer space. This ion is a one-electron species like a neutral hydrogen atom. Calculate the energy of the photon emitted for the transition from the n = 5 to the n = 3 state in this ion using the equation: En = − Z2/n2 (2.179 × 10−18 J). Z is the positive charge of the nucleus and n is the principal quantum number. In what part of the electromagnetic spectrum does this radiation lie?
• identify an orbital (as 1s, 3p, etc.) from its quantum numbers, or vice versa.
Ozone in the stratosphere absorbs ultraviolet light of wavelengths shorter than 320 nm, thus filtering out the most energetic radiation from sunlight. During this absorption, an ozone molecule absorbs a photon, which breaks an oxygen-oxygen bond, yielding an oxygen molecule and an oxygen atom: O3(g)+hvO2(g)+O(g) (Here, hv denotes a photon.) Suppose a flask of ozone is irradiated with a pulse of UV light of wavelength 275 nm. Assuming that each photon of this pulse that is absorbed breaks up one ozone molecule, calculate the energy absorbed per mole of O2 produced, giving the answer in kJ/mol.

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