For this problem it gives it shows us para attack. Please show all steps on how to solve it for ortho attack and why it is not favored? Theory of Directing Effects -NO₂; assume meta attack. NO₂ NO₂ fast - H &-&-&-&:] + & NO₂ NO₂ NO₂ +NO₂ NO₂ S. slow NO₂+ (a) NO₂ H NO₂ (d) - H (e) NO₂ (b) ▶ -NO₂; assume para attack. ► Contributor (e) places positive charge on adjacent atoms. NO₂ H NO₂ the most disfavored contributing structure NO₂ H NO₂ (e) NO₂ positive charges on adjacent atoms destabilize the intermediate + (c) NO₂ H HNO₂ (1) NO₂ NO₂ NO₂ ortho attack would similarly yield 3 contributing structures, one with the positive charge adjacent to -NO₂

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Chapter1: Chemical Foundations
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For this problem it gives it shows us para attack. Please show all steps on how to solve it for ortho attack
and why it is not favored?
Theory of Directing Effects
▶ -NO₂; assume meta attack.
NO₂
Sw=
+NO₂*
NO₂
slone
NO₂+
NO₂
slow
(a)
H
NO₂
NO₂
H NO₂
(d)
H
J
(e)
NO₂
(b)
-NO₂; assume para attack.
► Contributor (e) places positive charge on adjacent atoms.
NO₂
H
NO₂
the most disfavored
contributing structure
NO₂
HNO₂
(e)
NO₂
positive charges
on adjacent atoms
destabilize the
intermediate
(c)
NO₂
H
NO₂
H NO₂
(1)
fast
-
fast
H
It
NO₂
NO₂
NO₂
NO₂
ortho attack would similarly
yield 3 contributing structures,
one with the positive charge
adjacent to -NO₂
Transcribed Image Text:For this problem it gives it shows us para attack. Please show all steps on how to solve it for ortho attack and why it is not favored? Theory of Directing Effects ▶ -NO₂; assume meta attack. NO₂ Sw= +NO₂* NO₂ slone NO₂+ NO₂ slow (a) H NO₂ NO₂ H NO₂ (d) H J (e) NO₂ (b) -NO₂; assume para attack. ► Contributor (e) places positive charge on adjacent atoms. NO₂ H NO₂ the most disfavored contributing structure NO₂ HNO₂ (e) NO₂ positive charges on adjacent atoms destabilize the intermediate (c) NO₂ H NO₂ H NO₂ (1) fast - fast H It NO₂ NO₂ NO₂ NO₂ ortho attack would similarly yield 3 contributing structures, one with the positive charge adjacent to -NO₂
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