5. For the following molecule, how many isomeric forms of alkenes could be made by reacting this with sodium isopropoxidelalkoxide of isopropyl alcohol) in isopropyl alcohol solution at 75 Co? Show the process for the reaction and label and name all products expected to be made. Which one product is likely the major product? Remember E/Z as you name them. th
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- 5. For the following molecule, how many isomeric forms of alkenes could be made by reacting this with sodium isopropoxide (alkoxide of isopropyl alcohol) in isopropyl alcohol solution at 75 Cº? Show the process for the reaction and label and name all products expected to be made. Which one product is likely the major product? Remember E/Z as you name them. thIV. Complete the equations for the following reactions. Show all organic alkene products form, mechanism, indicate the major product and the rule Ş(CH3)2 NaSH HEAT OH™ HEATces to access important values if needed for this question. Complete the equation for the following reaction by drawing a structural formula for the missing organic product. CH3CH2NH2 H20 CH,CH,C-OH • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Draw cations and anions in separate sketchers. P. opy aste C. [F Visited CH4 M) M) M) ChemDoodle Submit Answer Retry Entire Group 5 more group attempts remaining
- Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.HN CH3 The synthesis of methamphetamine from benzene involves several reactions, one of which is shown below. Draw the major organic product(s) of the following reaction: Hg(OAc)2, H₂O; NaBH4 product You do not have to consider stereochemistry. Include counterions on quaternary ammonium ions. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.CH3 CH3 Br- Br2 .CH3 CH2Cl2 CH3 H3C H3C Br Electrophilic addition of bromine, Brɔ, to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl,. In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions CH3 CH3 CH3 CH3 H3C H3C :Br: :Br:
- Emarks here on the bookmarks bar. Import bookmarks now... Draw a structural formula for the major product of the reaction shown. H3C ● H3C ● C=CH₂ ctivity.do?locator= assignment-take Br₂ H₂O Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. // [References] O- [FDraw structural formulas for all alkenes that could be used to prepare the alcohol shown below by oxymercuration. CH3 1. Hg(ОAc)2, Н0 ? 2. NABH4 CH3 HO- • You do not have to consider stereochemistry. • Include only alkenes that will give the alcohol as the single major product. • Separate structures with + signs from the drop-down menu.10. Terpene is a class of naturally occurring molecules, found in many essential oils from plants, that share the same alkene features. All terpenes have a similar 5 carbon unit that includes an alkene thought to be biologically synthesized from the molecule isoprene. All terpenes are biosynthesized from molecules with the good leaving group: pyrophosphate (OPP). Loss of this OPP leads to the formation of a resonance stabilized carbocation. The new carbocation can undergo a nucleophilic attack from a T-bond as seen in acid-catalyzed hydration and hydrohalogenation, forming a new carbocation. This new carbocation can undergo an E1 reaction to form a new alkene. Add the curved arrows of the following reaction. hopp COPP D 5 R-carvone (spearmint oil) - Q Search 40 6 & COPP 1 COPP COPP
- Q3. For the following reactions, predict the products, mechanism and name all the products 4.2-hexene + chlorine gas5.Halogenation of cyclohexane in the presence of light and catalyst6.Sulfonation of Cyclobutane with oleum 7.Addition of HBr to methylcyclopropaneAn alkene having the molecular formula C,H12 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. CH3CH2CH,CH½CH2CH Draw a structural formula for the alkene. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. P opy aste Previous NextDraw structural formulas for all alkenes that could be used to prepare the alcohol shown below by oxymercuration. CH3 C ? 1. Hg(OAc)2, H₂O 2. NaBH4 -CH3 C P opy aste OH • You do not have to consider stereochemistry. • Include only alkenes that will give the alcohol as the single major product. • Separate structures with + signs from the drop-down menu.