3. Heat exchange between water and a reaction: Dry ice is solid carbon dioxide. Instead of melting, solid carbon dioxide sublimes according to the equation, CO2(s)→ CO2(g) Last night when I was out clubbing, I went back stage to see how their fog machine worked. It turns out that the entire fog machine was comprised of 10.0 L of water at 85.0°C, some dry ice, a fan and some tubing. When dry ice is put into the hot water, the dry ice sublimes to CO₂(g). The CO₂(g) and some H₂O(g) form fog that then gets blown by the fan through the tubing. Assuming no heat loss to the surroundings (and that all of the heat lost by the water cooling goes to sublime the dry ice), I immediately calculated the grams of dry ice that were needed to exactly cool the water from 85.0°C to 10.0°C. I needed to recall that AH f for CO₂(s) is -427.4kJ/mol (I always go out with Tro, but even the text didn't have this piece of info). A. What is AH°rxn for the sublimation of CO₂? To calculate this, use the AHf values for the sublimation reaction. B. How many grams of CO₂(s) did I calculate? C. How many L of CO₂ gas at 1 atm and 22°C would be created?

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Chapter8: Thermochemistry
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3. Heat exchange between water and a reaction: Dry ice is solid carbon dioxide. Instead of melting, solid carbon dioxide sublimes
according to the equation,
CO₂(s) → CO₂(g)
Last night when I was out clubbing, I went back stage to see how their fog machine worked. It turns out that the entire fog machine
was comprised of 10.0 L of water at 85.0°C, some dry ice, a fan and some tubing. When dry ice is put into the hot water, the dry ice
sublimes to CO₂(g). The CO₂(g) and some H₂O(g) form fog that then gets blown by the fan through the tubing.
Assuming no heat loss to the surroundings (and that all of the heat lost by the water cooling goes to sublime the dry ice), I
immediately calculated the grams of dry ice that were needed to exactly cool the water from 85.0°C to 10.0°C. I needed to recall that
AH f for CO₂(s) is -427.4kJ/mol (I always go out with Tro, but even the text didn't have this piece of info).
A. What is AH°rxn for the sublimation of CO₂? To calculate this, use the AHf values for the sublimation reaction.
B. How many grams of CO₂(s) did I calculate?
C. How many L of CO₂ gas at 1 atm and 22°C would be created?
Transcribed Image Text:3. Heat exchange between water and a reaction: Dry ice is solid carbon dioxide. Instead of melting, solid carbon dioxide sublimes according to the equation, CO₂(s) → CO₂(g) Last night when I was out clubbing, I went back stage to see how their fog machine worked. It turns out that the entire fog machine was comprised of 10.0 L of water at 85.0°C, some dry ice, a fan and some tubing. When dry ice is put into the hot water, the dry ice sublimes to CO₂(g). The CO₂(g) and some H₂O(g) form fog that then gets blown by the fan through the tubing. Assuming no heat loss to the surroundings (and that all of the heat lost by the water cooling goes to sublime the dry ice), I immediately calculated the grams of dry ice that were needed to exactly cool the water from 85.0°C to 10.0°C. I needed to recall that AH f for CO₂(s) is -427.4kJ/mol (I always go out with Tro, but even the text didn't have this piece of info). A. What is AH°rxn for the sublimation of CO₂? To calculate this, use the AHf values for the sublimation reaction. B. How many grams of CO₂(s) did I calculate? C. How many L of CO₂ gas at 1 atm and 22°C would be created?
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