1,3-Cyclopentadiene has to be used quickly after it is made, or stored cold. Which reaction below is the reason it has to be used so quickly? 10.1-0 A B C + H₂O HO D + H2O S OH O O C O D A B
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- Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nah7-55 trans-1-Bromo-2-methylcyclohexane yields the non-Zaitsev elimination product 3-methylcyclohexene on treatment with KOH. What does this result tell you about the stereochemistry of E2 reactions? CH3 .CH3 кон Br H trans-1-Bromo-2-methylcyclohexane 3-MethylcyclohexeneWhat are the reagents A and B in the scheme below? Br CH3 в CH,CH,CH,C-CH, A HgC CHy H;C CH
- Reactions: Draw the Structure(s) of the Product(s) + Br2 + HBr он KMNO4 lots of + HBr H2SO4 OH 180 °CThe correct sequence of reagents for the following conversion is: Br N T OH Br OH BrElimination reactions of cis- and trans-1-bromo-2-methylcyclohexanes with Eto in ETOH could potentially give the two products, 1-methylcyclohexene (1) or 3-methylcyclohexene (2). Which answer (a-d) indicates the major products for each reaction? Br „Br EtO Eto "CH3 ELOH `CH3 *CH ELOH "CH3 cis trans Select one: a. 2 from the cis and 1 from the trans substrate b. 2 both from the cis and trans substrates c. 1 both from the cis and trans substrates d. 1 from the cis and 2 from the trans substrate
- Identify the reagents needed for the given reaction. -c-CH3 || Ĉ-CH3 || ċ-CH2B1 Select one: HBr О НBr O Br2, H20 O Br2, hv O Br2, OHWhich of the following reagents would you use to prepare Chlorocyclopentane from cyclopentene? OC2 / H20 NBS / H20, DMSO OCh/ CH,Cl2 HCIDichlorocarbene can be generated by heating sodium trichloroacetate. Propose a mechanism for the reaction, and use curved arrows to indicate the movement of electrons in each step. What relationship does your mechanism bear to the base-induced elimination of HC1 from chloroform?
- Provide the mechanism and products for the acid-catalyzed epoxide opening reactions below, including appropriate stereochemistry.8 What is the missing reactant in the following reaction? & A C ? C₂H50 NaOC₂H5 H* HOC2H5 H H B D OF C₂H50 =O O CI O= OC₂H5 OCH59:33 AM Tue 25 Jan * 99% Assignment 5 What products would you expect from the following reactions? (a) CH3CH2CH2C=CH + 1 equiv Cl2 → ? (b) CH3CH2CH2C=CCH2CH3 1 equiv HBr (c) CH3 CH;CHCH,C=cCH,CH3 Lindlar + H2 ? catalyst