EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 16.3, Problem 5CC
Draw an energy diagram showing the relative energy levels of the
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Calculate the bond energy of C-F given that the heat of atominzation of CHFClBr is 1502 kj/mol, and that the bond energies of C--H, C--Br, and C-Cl are 413, 276 and 328 kj/mol, respectively. show the calculations
Draw what you expect the 1H spectra of the four compounds to be.
or each of the following molecules, construct the MOS
from the 2p, atomic orbitals perpendicular to the plane of
the carbon atoms.
(a) Cyclobutadiene HC=CH
НС—СН
HC=CH
НС —СH
(b) Allyl radical
H
H
H
H
C=C
•C-C,
H
C-H
H
C-H
H
H
Indicate which, if any, of these orbitals have identical ener-
gies from symmetry considerations. Show the number of
electrons occupying each w MO in the ground state, and
indicate whether either or both of the molecules are para-
magnetic. Assume that the C atoms in the allyl radical are
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Activate
io to S
Chapter 16 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 16.1 - Prob. 1CCCh. 16.2 - Prob. 2CCCh. 16.2 - Prob. 3CCCh. 16.2 - Prob. 4CCCh. 16.3 - Draw an energy diagram showing the relative energy...Ch. 16.4 - Prob. 1LTSCh. 16.4 - Prob. 6PTSCh. 16.4 - Prob. 7PTSCh. 16.5 - Prob. 2LTSCh. 16.5 - Predict the products for each of the following...
Ch. 16.5 - Prob. 10PTSCh. 16.5 - Prob. 12CCCh. 16.7 - Prob. 3LTSCh. 16.9 - Prob. 20CCCh. 16.9 - Prob. 4LTSCh. 16.9 - Prob. 21PTSCh. 16.10 - Prob. 23CCCh. 16.10 - Prob. 26CCCh. 16.11 - Prob. 5LTSCh. 16 - Prob. 30PPCh. 16 - Prob. 31PPCh. 16 - Prob. 32PPCh. 16 - Prob. 34PPCh. 16 - Prob. 35PPCh. 16 - Prob. 36PPCh. 16 - Prob. 37PPCh. 16 - Prob. 38PPCh. 16 - Prob. 39PPCh. 16 - Prob. 40PPCh. 16 - Prob. 41PPCh. 16 - Prob. 42PPCh. 16 - Prob. 44PPCh. 16 - Prob. 45PPCh. 16 - Prob. 46PPCh. 16 - Prob. 54PPCh. 16 - Prob. 55PPCh. 16 - Prob. 56PPCh. 16 - Prob. 68IPCh. 16 - Prob. 72IPCh. 16 - Prob. 73IPCh. 16 - Prob. 74IPCh. 16 - Prob. 75IPCh. 16 - Prob. 76IPCh. 16 - Prob. 77IP
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