the reaction and rate law for the gas phase decomposition ofdinitrogen pentaoxide are 2N205(g)--->4NO2(g) +O2(g) rate= k[N205] which of the following can be considered valid mechanisms forthe reaction? I) one-step collision II) 2N2O5(g)--->2NO3(g) +2NO2(g) [slow] 2NO3(g)--->2NO2(g) +20(g) 20(g)--- [fast]

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 14.14CYU: One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall...
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the reaction and rate law for the gas
phase decomposition
ofdinitrogen
pentaoxide are
2N205(g)--->4NO2(g)
+O2(g) rate=
k[N205]
which of the following can be considered
valid mechanisms forthe reaction?
I) one-step collision
II) 2N2O5(g)--->2NO3(g)
+2NO2(g)
[slow]
2NO3(g)--->2NO2(g)
+20(g)
20(g)---
>02(g)
[fast]
III) N205(g)<====>NO3(g) +NO2(g)
[fast]
NO2(g) + N2O5(g) ---> 3NO2(g)+ O(g)
[slow]
NO3(g) + O(g)---> NO2(g) +O2(g)
[fast]
IV) 2N2O5(g)<===> 2NO2(g) +
[fast]
N203(g)+30(g) [fast]
N203(g) + O(g)---
>2NO2(g)
20(g)---
>O2(g)
V)2N2O5(g)---
>N4010(g)
+02(g)
[slow]
N4010(g)---> 4NO2(g)
[fast]
[fast]
[slow]
Transcribed Image Text:the reaction and rate law for the gas phase decomposition ofdinitrogen pentaoxide are 2N205(g)--->4NO2(g) +O2(g) rate= k[N205] which of the following can be considered valid mechanisms forthe reaction? I) one-step collision II) 2N2O5(g)--->2NO3(g) +2NO2(g) [slow] 2NO3(g)--->2NO2(g) +20(g) 20(g)--- >02(g) [fast] III) N205(g)<====>NO3(g) +NO2(g) [fast] NO2(g) + N2O5(g) ---> 3NO2(g)+ O(g) [slow] NO3(g) + O(g)---> NO2(g) +O2(g) [fast] IV) 2N2O5(g)<===> 2NO2(g) + [fast] N203(g)+30(g) [fast] N203(g) + O(g)--- >2NO2(g) 20(g)--- >O2(g) V)2N2O5(g)--- >N4010(g) +02(g) [slow] N4010(g)---> 4NO2(g) [fast] [fast] [slow]
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