For each organic molecule (shown below) give the oxidation products formed by: B (1). KMnO4 (in aqueous solution of H2SO4 at room-temperature experimental reaction conditions). • (2). KMnO4 (in hot aqueous solution of H2SO4). (1) (3) OH OH (2) OH OH (4) OH OH
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- (d) When butane, CHSCH:CH:CHsand bromine gas, Brz is exposed to sunlight, monobrominated product are produced. The reaction equation is glven below: Apabila butana, CH:CH2CH2CH3 dan gas bromin, Brz terdedah kepada cahaya matahari, produk pembrominan tunggal dihasilkan. Persamaan tindak balas diberikan di bawah: UV CH;CH,CH,CH, - Bry B.10. The following reaction has variation of free energy value of AG = -2.1 kJ/mol CH;Br + H2S 2 CH;SH + HBr (a) Calculate Keq at room temperature (25°C) for this reaction as written. (b) Starting with a 1 M solution of CH3B and H2S, calculate the final concentrations of all four species at equilibrium.(b) Describe the hazards of (i) trioxygen: (ii) hydroxide ion; (ii) hydrogen sulfide. (c) Explain why an aqueous solution of sodium sulfide has an odor of hydrogen sulfide. (d) (11) Reduction of H,CCHCHO with NABH4 gives a product different from that of catalytic hydrogenation (H2 /Ni). What are the products?
- (b) Predict the suitable solvent (H2O or CH3COCH:) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr (ii) H,C- CH31. What is the major organic product obtained from the following reaction? (1pt) 1 O-tBu 2 KOTBU Br O-tBu 3 Br O-tBu a. b. с. d. 1234(a) Draw the structures ofA to E in the following reactions. он 1. LIAIH, 2. H0 PCC 00 Lindiar's catalyst OH (CH,COOH THOCHICH,lla (*DET 1. RCOH 2. HO
- 1. Provide the structure of the product and write the mechanism of its formation for the following reactions: And can you explain in details what actually happens to get the products formed. (d) H* ? (e) но- H,SO, (f) OH NH2 NANO,, HCI ?Is this reaction a feasible method of removing SO2? Why or why not?1. (4) Complete the reaction and show the mechanism Br (CH3)2NH (xs)
- 6.) Predict the product of the following chemical reactions and state where the product (waste) should the waste should be disposed: Example: он 1. Nallif, ethanol 2. 10 CH,CH,CH,CH CH,CH,CH,CH H Butanal 1-Butanol Waste: G704 (Non-halogenated organic solvents) 1. Nalil, ethanal a.) Cyclohexanecarbaldehyde 2 110 b.) Sodium Flouride + 3-iodo-3-methylpentane (hìnt: substitution or elimination?) H,O c.) Benzoic acid + Phenol PCC d.) 3-pentanol H.CrO> e.) Cyclohexylmethanol1. Draw the structure of the major products of the following reactions -OH (1) DMSO, (COCI)2 (2) EtgN A. H,CrO, В. (1) KMNO,, HO", A OH (2) H,O* С.(b) Predict the suitable solvent (H2O or CH3COCH3) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH NaBr H,C CH (ii)