1. (a) A study was made of the effect of hydroxide ion, OH-, concentration on the rate for the following reaction: (aq) + OCH(aq) 10-(aq) + Cl(aq) Experimental data: [OCI-] [OH-] Rate M/sec 0.0013 0.012 0.1 0.0026 0.012 0.1 9.4 X 10-3 18.7 X 10-3 0.0013 0.006 0.1 0.0013 0.018 0.1 0.0013 0.012 0.05 0.0013 0.012 0.2 0.0013 0.018 0.2 4.7 X 10-3 14.0 X 10-3 18.7 x 10-3 4.7 X 10-3 7.0 X 10-3 Determine the rate law and the value of the rate constant, k.

1. (a) A study was made of the effect of hydroxide ion, OH-, concentration on the rate for the following reaction: (aq) + OCH(aq) 10-(aq) + Cl(aq) Experimental data: [OCI-] [OH-] Rate M/sec 0.0013 0.012 0.1 0.0026 0.012 0.1 9.4 X 10-3 18.7 X 10-3 0.0013 0.006 0.1 0.0013 0.018 0.1 0.0013 0.012 0.05 0.0013 0.012 0.2 0.0013 0.018 0.2 4.7 X 10-3 14.0 X 10-3 18.7 x 10-3 4.7 X 10-3 7.0 X 10-3 Determine the rate law and the value of the rate constant, k.

Chemistry for Engineering Students

3rd Edition

ISBN:9781285199023

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.56PAE: The labels on most pharmaceuticals state that the medicine should be stored in a cool, dark place....

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*[I]*	*[OCl–]*	*[OH–]*	*Rate M/sec*
0.0013	0.012	0.1	9.4 x 10-3
0.0026	0.012	0.1	18.7 x 10-3
0.0013	0.006	0.1	4.7 x 10-3
0.0013	0.018	0.1	14.0 x 10-3
0.0013	0.012	0.05	18.7 x 10-3
0.0013	0.012	0.2	4.7 x 10-3
0.0013	0.018	0.2	7.0 x 10-3